Synthesis, Characterization and Application of Multi-Generations Hyperbranched Polyurethane Based on Isophorone Diisocyanate

Abstract:

A series of different generation hyperbranched polyurethane(HBPU) was synthesized based on the raw materials of isophorone diisocyanate(IPDI) and diethanolamine(DEOA). Their structure, thermal degradation mechanism and glass transition temperature(Tg) were characterized by fourier transform infrared spectroscopy(FTIR), nuclear magnetic resonance spectroscopy(NMR), thermal gravimetric analysis(TGA) and differential scanning calorimetry(DSC). The results showed that: the yield of each generation HBPU was up to 90%, different generation HBPU had almost the same initial degradation temperature(about at 200°C) and they all had two decomposition platforms; with the increase of generation, Tg increased from 107.2°C to 132.1°C. The gloss and hardness of the HBPU coatings were significantly improved.

• Periodical: Advanced Materials Research (Volumes 554-556)
• Pages: 126-129
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.554-556.126
• Online since: July 2012
• Authors: Shun Yin, Ning Sun*, Chun Yun Feng, Zhi Mou Wu, Zhao Hua Xu, Shao Hua Jiang
• Keywords: Coating, Generation, Hyperbranched Polyurethane, Synthesis

References

[1] Jena K K, Chattopadhyay D K, Raju K V S N. European Polymer Journal, 2007, 43(5):1825-1837.

[2] JIN Jia,WU Yong-Gang, et al. Chemical Journal of Chinese Universities, 2010, 31(5):1023-1028.

[3] Chickiyan Sivakumar. Journal of Applied Polymer Science, 2011, 120(2):725-734.

[4] Harekrishna Deka, Niranjan Karak. Polymers for Advanced Technologies, 2011, 22(6):937-980.

[5] Dong Lin, Bing Liu, Lei Xu. Journal of Applied Polymer Science, 2011, 121(2):957-963.

[6] Rama Shanker Mishra, A.S. Khanna. Organic Coatings, 2011, 72(4):769-777.

[7] Sun Ning, Liu Yu-Hang, et al. Chemical Journal of Chinese Universities, 2011, 32(7):1639-1644.

[8] Hepburn C. Polyurethane Elastomers[M]. New York:Applied Science Publishers, 1982:290-294.

[9] Abdelrehim M, Komber H, et al. Polym. Sci. Part A: Polym. Chem., 2004, 42(12):3062-3081.

[10] Kishore K J, Raju K V S N. Ind. Eng. Chem. Res., 2008, 47(23):9214-9224.

[11] Zoran S.Petrović, Zoltan Zavargo, et al. Applied Polymer Science, 1994, 51(6):1087-1095.

[12] Erickson KL. Journal of Thermal Analysis and Calorimetry, 2007, 89(2):427-440.

[13] Petrovic Z S,Javni I,Guo A et al. Jouranl of Applied Polymer Science, 2000, 77(8):1723-1734.