Scaling Mechanism of Heat Exchanger for Spent Sulfuric Acid Concentrating in Titania Production

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Abstract:

The component and contents of scale sample on the graphite heat exchanger were analyzed by ED-XRF( Energy dispersive X-ray fluorescence spectrometer) and the component and contents of spent acid unconcentrated and concentrated were measured by AAS(atomic absorption spectrometer).In addition, the phase structure of scale sample was tested by XRD(X-ray diffraction) and the simulation experiment of spent acid concentrating was carried out to study the scaling mechanism in the laboratory. The results show that the main components of scale were Ca, Ti and Fe. The scaling might be induced by settlement of Ti oxide, and then Ca and Fe precipitate rapidly.

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Advanced Materials Research (Volumes 560-561)

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678-681

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August 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] Chen Yongchang,Ma Zhongfang,Xing Xiaogai,and Chen Xiaozhuan.Experimental Study of Fouling Mechanism on Heat Tranfer Surface, J. Journal of Beijing University of Technology, 31(2005) 86-88.

Google Scholar

[2] Gong Jiazhu, Jiang Xiuying,and Yuan Fengbo,Present status and development direction of concentration technique research on spent acid of sulfate process titanium dioxide, J.Norganic Chemicals Industry,40(2008)1-3.

Google Scholar

[3] Tang Wenqian, Li Haiquan, The Technology Development of Titanium Dioxide Industry by Sulfate Process, J.Chemical Engineering Design, 4(2003).

Google Scholar

[4] Gabriel Denecker, Werner Verhoeven., Proeess for The Produetion of High-gradeTitanium Dioxid By Sulfate Method,Wiley, New York, 1993.

Google Scholar

[5] Tang Wenyuan,Wang Xiaoying, The introduce and comment of concentration technique research on spent acid of sulfate process titanium dioxide,J.Chemical Engineering Design, 20(2010) 3-6.

Google Scholar

[6] He Zhangliang,Zeng Dongmei, The Comprehensive Utilization of Titanium Dioxide Spent Acid,J.Inorganic Chemicals Industry, 6(2002)31.

Google Scholar

[7] Zhuo Xuefeng, Xu Honghui, The Modifications of Production Techniques of Spent Acid Concentration,J.Chinese Chlor-alkali,11(2002).

Google Scholar

[8] Ye Shuzi, Approach to a New Technology for Concentration of Spent Acid from Titanium Pigment Production,J.Sulphuric Acid Industry,3(2007)9-12.

Google Scholar