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Fabrication of Supramolecular Structured Hydrogels Based on Diels-Alder Click Reaction
Abstract:
A novel kind of supramolecular structrued hydrogels were fabricated by Diels-Alder click reaction between furan-functionalized polypseudorotaxanes and polymeric dienophiles. Firstly, polypseudorotaxanes were prepared by supramolecular self-assembly of furan-terminated poly(ethylene glycol)(PEG) and α-cyclodextrins (CDs) in water. And polymeric dienophiles were synthesized by a coupling reaction between copolymer of hydroxyethyl methacrylate and N,N-dimethyl acrylamide and N-maleoyl alanine (AMI). The supramolecular structured hydrogels were prepared by Diels-Alder reaction in water.
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405-408
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August 2012
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© 2012 Trans Tech Publications Ltd. All Rights Reserved
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