Synthesis and Characterization of a Novel Star-Shaped Polymers with Biological Compatibility via Ring-Opening Polymerization and Atom Transfer Radical Polymerization

Shi Biao Zhou; An Guo Xiao; Yuan Dao Chen; Yong Bing Zhuan; Yun Wang

doi:10.4028/www.scientific.net/AMR.602-604.727

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Synthesis and Characterization of a Novel Star-Shaped Polymers with Biological Compatibility via Ring-Opening Polymerization and Atom Transfer Radical Polymerization
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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 602-604Synthesis and Characterization of a Novel...

Synthesis and Characterization of a Novel Star-Shaped Polymers with Biological Compatibility via Ring-Opening Polymerization and Atom Transfer Radical Polymerization

Abstract:

Hydroxyl functional hyperbranched polyester initiators initiated the ring-opening polymerization(ROP) of ε-caprolactone (CL) and the star-shaped polymer with PCL arms using hyperbranched polyester as nuclear was produced. Then, the bromide of star-shaped polymer, initiated the atom transfer radical polymerization (ATRP) of oligo(ethylene oxide) methacrylate (OEOMA) and the star-shaped polymer containing the arms of PCL-b-POEOMA was synthesized ,and the characterization of polymer structure was investigated by NMR.

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Periodical:

Advanced Materials Research (Volumes 602-604)

Pages:

727-731

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.602-604.727

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Online since:

December 2012

Authors:

Shi Biao Zhou, An Guo Xiao, Yuan Dao Chen, Yong Bing Zhuan, Yun Wang

Keywords:

ATRP, PCL, POEOMA, ROP, Star-Shaped Polymer

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