Efficient Synthesis, Properties of a Novel Unsymmetrical Photochromic Diarylethene Based on Trifluoromethy Group and Formyl Group

Gang Liu; Long Liang; Duo Hua Jiang

doi:10.4028/www.scientific.net/AMR.602-604.892

Paper Titles

Characteristic of the Pigments in Castanea mollissina Shell
p.874

A New Methodology to Predict Energy Bandgaps in Ga_xIn_1-xAs_yP_1-y Compounds by ANFIS Theories
p.879

Time-Dependent Density Functional Theory Studies of Plasmons in Parallel Double Sodium Atomic Chains
p.883

Studies on Extraction Equilibrium of Rare Earths in Ion Liquid Extraction System Using 1-Butyl-3-Methyl-Imidazolium Hexafluorophosphate and 1-Phenyl-3-Methyl-4-Benzoyl-Pyrazolone-5
p.887

Efficient Synthesis, Properties of a Novel Unsymmetrical Photochromic Diarylethene Based on Trifluoromethy Group and Formyl Group
p.892

Photoinduced Fluorescence Switching of a New Diarylethene and its Application in Optical Recording Storage
p.896

Synthesis, Properties and Application of a Photochromic Diarylethene with a Dithiolane Unit
p.900

Synthesize, Photochromic and Application for Optical Recording of Diarylthene Bearing Naphthyl Unit
p.904

The Composite Catalysts Used for Cotton Denim Resin Wrinkles Setting
p.908

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 602-604Efficient Synthesis, Properties of a Novel...

Efficient Synthesis, Properties of a Novel Unsymmetrical Photochromic Diarylethene Based on Trifluoromethy Group and Formyl Group

Abstract:

An unsymmetrical diarylethene derivative was synthesized, and its photochromic properties and fluorescence switch were investigated in detail. The results showed that this compound exhibited reversible photochromism, undergoing reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light both in solution and in PMMA film, and its absorption maxima were observed at 599 nm in hexane and at 609 nm in PMMA amorphous film, respectively, upon irradiation with 297 nm UV light. The fluorescence intensity of diarylethene decreased dramatically along with the photochromism from open-ring isomer to closed-ring isomer upon irradiation with 297 nm light in PMMA. In hexane solution, the open-ring isomer of the diarylethene 1 exhibited relatively strong fluorescence at 419 nm when excited at 309 nm. The fluorescence intensity is highest at the concentration of 5.0×10^-5 mol/L when excited at 309 nm.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 602-604)

Pages:

892-895

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.602-604.892

Citation:

Cite this paper

Online since:

December 2012

Authors:

Gang Liu, Long Liang, Duo Hua Jiang

Keywords:

Cyclization, Diarylethene, Fluorescence Switching, Photochromism

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] S. Kobatake, M. Irie, Chemistry Letters, Japan, vol. 32, (2003), p.1078.

Google Scholar

[2] P. D. Patel, A. E. Masunov, The Journal of Physical Chemistry A, vol. 113, (2009), 8409.

Google Scholar

[3] B. L. Feringa, Molecular Switches, Wiley-VCH, Weinheim, Germany, (2001).

Google Scholar

[4] S. Z. Pu, G. Liu, L. Shen, J. K. Xu, Organic Letters, vol. 9, (2007), p.2139.

Google Scholar

[5] J. K. W. Lee, C. C. Ko, K. M. C. Wong, N. Y. Zhu, V. W. W. Yam, Organometallics, vol. 26, (2007), p.12.

Google Scholar

[6] Y. L. Feng, Y. L. Yan, S. Wang, W.H. Zhu, S.X. Qian, H. Tian, Journal of Mathematical Chemistry, vol. 16, (2006), p.3685.

Google Scholar

[7] M. Irie, Chemical Reviews., vol. 100, (2000), p.1685.

Google Scholar

[8] H Tian, S. J Yang, Chemical Society Reviews, vol. 33, (2004), p.85.

Google Scholar

[9] S. Z. Pu, TS. Yang, J. K. Xu, B. Chen, Tetrahedron Letters , vol. 47, (2006), p.6473.

Google Scholar

[10] S.Z. Pu, Q. Xiao, J.K. Xu, L. Shen, G.Z. Li, B. Chen, Chinese Journal of Chemistry, vol. 24, (2006), p.463.

Google Scholar

[11] S. Z. Pu, J. K. Xu, L. Shen, Q. Xiao, T. S. Yang, G. Liu, Tetrahedron Lett. vol. 46, (2005), p.871.

Google Scholar

[12] C. B. Fan, S. Z. Pu, G. Liu, T. S. Yang, Journal of Photochemistry and Photobiology A, vol. 194, (2008), p.333.

Google Scholar

[13] T. Norsten, N. Branda, Journal of the American chemical society, vol. 123, (2001), p.1784.

Google Scholar

[14] F. Tuyoshi, K. Tsuyoshi, K. Seiya, M. Irie, The Journal of Physical Chemistry B, vol. 107, (2003), p.8372.

Google Scholar