Effect of H2 in CO Feed Gas on Carbonylation of Methanol to Acetic Acid over Ir-Ru Catalysts

Bo Liu; Sheng Fu Ji

doi:10.4028/www.scientific.net/AMR.610-613.2600

Paper Titles

Airport Noise Environmental Impact Assessment Based on the Multi-Level Fuzzy Comprehensive Evaluation
p.2578

Modeling and Analysis of Piezoelectric Bimorph Cantilever for Vibration Energy Harvesting
p.2583

The Application of Corrosion and Scale Inhibitor to Circulating Water
p.2591

Simulation and Adjustment of the Potential of Cleaner Production Based on System Dynamics in Liao River Basin
p.2595

Effect of H₂ in CO Feed Gas on Carbonylation of Methanol to Acetic Acid over Ir-Ru Catalysts
p.2600

Study and Practice of Fine Sand Recovery and Wastewater Cleaning System for Xinkaiyuan Crushed Stones Company
p.2606

Comprehensive Information Management System for Cleaner Production
p.2613

Study on the Method for Cleaning the Filter Bags Used in Baghouse
p.2617

Technology to Control PCDD/Fs from MSW Incineration Processes
p.2621

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 610-613Effect of H2 in CO Feed Gas on Carbonylation of...

Effect of H₂ in CO Feed Gas on Carbonylation of Methanol to Acetic Acid over Ir-Ru Catalysts

Abstract:

Effect of the minor H₂ presence in CO feed gas on the carbonylation of methanol to acetic acid over homogeneous Ir-Ru catalysts was studied. The results indicated that the carbonylation reaction rate would be decreased with the increasing of H₂ content in CO feed gas. The process of CO migratory insertion was inhibited with the decrease of CO partial pressure in feed gas. With the increasing of H₂ content in CO feed gas, CH₄ composition distribution in gas byproducts was increased while that of CO₂ was decreased. The yield of propionic acid in liquid products was increased. The occurrence extent of hydrogenated side reactions was affected due to minor H₂ presence.

You might also be interested in these eBooks

Progress in Environmental Science and Engineering

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 610-613)

Pages:

2600-2605

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.610-613.2600

Citation:

Cite this paper

Online since:

December 2012

Authors:

Bo Liu, Sheng Fu Ji

Keywords:

Acetic Acid, Carbonylation, H₂, Ir-Ru Catalysts, Methanol

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] N. Yoneda, S. Kusano and M. Yasui: Applied Catalysis A: General Vol. 221 (2001), p.253

Google Scholar

[2] F.E. Paulik and J.F. Roth: Chemical Communications Vol. 24 (1968), p.1578

Google Scholar

[3] C.S. Garland, M.F. Giles, A.D. Poole and J.G. Sunley: EUR Patent 0,728,726. (1996).

Google Scholar

[4] M.J. Baker, M.F. Giles, C.S. Garland and M.J. Muskett, EUR Patent 0,752,406.(1997).

Google Scholar

[5] G.J. Sunley and D.J. Watson: Catalysis Today，Vol. 58 (2000), p.293

Google Scholar

[6] P.M. Maitlis, A. Haynes, G.J. Sunley and M.J. Howard: Journal of the Chemical Society, Dalton Transactions Vol 11 (1996), p.2187

Google Scholar

[7] A. Haynes, P.M. Maitlis, G.E. Morris, G.J. Sunley, H. Adams, P.W. Badger and C.M. Bower: Journal of the American Chemical Society Vol.126 (2004), p.2847

Google Scholar