Study on the Kinetic Spectrophotometric Determination of Selenium (IV) on Oxidation of Neutral Red with Potassium Periodate and its Application

Abstract:

Based on the oxidation of neutral red by KIO4 in 3.2×10-4 mol/L sulfuric acid solution, a simple kinetic spectrophotometric method was developed for the determination of trace amounts of Se(IV).The reaction was monitored spectrophotometrically by measuring the decrease in the absorbance of neutral red at 530 nm with a fixed-time method. The decrease in the absorbance of neutral red is proportional to the concentration of Se(IV) in the range 0.0–8.0 µg/L with a fixed time of 4–6 min from the initiation of the reaction. The limit of detection is 0.36 µg/L Se(IV). The influence of the factors such as acidity, concentration of reactants, reaction time, temperature and co-existing ions on the reaction is discussed. The optimum conditions of reaction are established and some kinetic parameters are determined. The apparent activation energy of catalytic reaction is 81.60 kJ/mol. The relative standard deviation for the determination of 0.1 and 0.2 µg/mL Se(IV) was 2.1 and 1.9 %, respectively. The method has been successfully applied to the determination of Se (IV) in tea and human hair samples with the relative standard deviation of 0.33 %–1.5 % and the recovery of 97.5 %–103.5 %.

• Periodical: Advanced Materials Research (Volumes 610-613)
• Pages: 446-451
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.610-613.446
• Online since: December 2012
• Authors: Zhi Rong Zhou, Li Zhen Zhang
• Keywords: Catalytic Spectrophotometry, Neutral Red, Potassium Periodate, Selenium (IV)

References

[1] X. Ziegel and A. Ziegel (Eds.): Concepts for Metal Ion Toxicity (Dekker, New York 1986).

[2] H. Parkman and H. Hultberg: IVL-Rapport (Swedish), Vol. B1486 (2002), p.1

[3] J.E. Spallholz, J.L. Martin and H.E. Ganther (Eds.): Selenium in Biology and Medicine (AVI Publishing Co. Inc., Westport, CT 1981).

[4] D. Wang, G. Alfthan, A. Aro, P. Lahermo and P. Vaananen: Agri. Ecosyst. Environ. Vol. 50 (1994), p.133

[5] F.A. Patty: Industrial Hygiene and Toxicology, Vol. II (Wiley Interscience, New York 1962).

[6] A.D. Shendrikar and P.W. West: Anal. Chim. Acta, Vol. 89 (1977), p.403

[7] J.R. Shapira: Organic Selenium Compounds their Chemistry and Biology (Wiley Interscience, New York 1971).

[8] APHA: Standard Methods for the Examination of Water and Wastewater, 19th ed. (American Public Health Association, Washington, DC 1995).

[9] L.K. Isaeev (Ed.): Control of Chemical and Biological Environmental Parameters (St. Petersburg, Krismas 1998).

[10] G.P. Bespamyatnov and Yu.A. Krotov: Maximum Permissible Concentrations of Chemical Compounds in the Environment (Khimiya, Moscow 1985).

[11] V. Badmaev and M. Majeed: Altern. Therap. Vol. 2 (1996), p.59

[12] M. Navarrete, A. Gaudry, G. Revel, T. Martinez and L. Cabrera: Biol. Trace Elem. Res. Vol. 79 (2001), p.97

[13] E. Meuillet, S. Stratton, D.P. Cherkuri, A.C. Goullet, J. Kagey, B. Porter.eld and M.A. Nelson: J. Cell. Biochem. Vol. 91 (2004), p.443

[14] L. K. Schumacher and M. Roy: BioFactors Vol. 14 (2001), p.161

[15] G.F. Combs Jr., L.C. Clark and B.W. Turnbull: Biofactors Vol. 14 (2001), p.153

[16] L.R. McDowell: Minerals in Animals and Human Nutrition (Academic Press, New York, 1992).

[17] J. Tan and Y. Huang: Water Air & Soil Pollut. Vol. 57–58 (1991), p.59

[18] R.L. Tatken and R.J. Lewis: Registry of Toxic E. ects of Chemical Substances (US Dept. Health and Human Science, Cincinnati, Ohio 1983).

[19] S. Zaichick and V. Zaichick: Applied Radiation and Isotopes Vol. 70 (2012), p.81

[20] S. Kamlesh and K.P. Devesh: Food Chemistry Vol. 124 (2011), p.1673

[21] P. Masson, D. Orignac and T. Prunet: Analytica Chimica Acta Vol. 545 (2005), p.79

[22] M.A. Khairia. Arabian Journal of Chemistry Vol. 2 (2009), p.95

[23] A.O. da S. Marcelo da S. and A. Z. A. Marco: Microchimica Acta Vol. 176 (2012), p.131

[24] C. Filipe, M. Miguel, C.M. Carlos, C. Ema, Ana I.R.N.A. Barros and M.N. Fernando: Journal of Food Composition and Analysis Vol. 24 (2011), p.351

[25] D. Leyva, J. Estévez, A. Montero and I. Pupo: Journal of Radioanalytical and Nuclear Chemistry Vol. 291(2012), p.699

[26] M. Darja, O. Jože and S. Vekoslava. Food Chemistry Vol. 107 (2008), p.75

[27] M. Dzierzgowska, K. Pyrzyñska and E. Poboży: Journal of Chromatography A  Vol. 984 (2003), p.291

DOI: 10.1016/s0021-9673(02)01846-0

[28] A. Mehdi and A. Alireza: Journal of Hazardous Materials Vol. 168 (2009), p.542

[29] A.M. Serra, J.M. Estela, B. Coulomb, J.L. Boudenne and V. Cerdà: Talanta Vol. 81 (2010), p.572

[30] Z.R. Zhou, Q. Wang, S.Y. Zhang, J.W. Zhang, Y.L. Zhang and Z.W. Su: Chinese journal of Food Science Vol. 29 (2008): p.292

[31] C. Vimlesh and P. Surendra: Journal of Hazardous Materials Vol.165 (2009), p.780

[32] G. Ramazan, İ.U. Halil, A. Mehmet and B. Pinar: Rare Metals Vol. 30 (2011), p.477