Preparation and Photocatalytic Activity of Heteropolyacid Supported on Titanium Dioxide Photocatalysts

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Abstract:

TiO2-based hybrid catalysts functioned by Keggin-type heteropolyacid, H3PW12O40/ TiO2, were prepared via one-pot co-condensation method in the presence of a triblock copolymer surfactant (F127). The materials were well characterized by FT-IR, UV-vis DRS spectroscopy methods, and X-ray diffraction analysis to confirm the structural integrity of the Keggin unit in the hybrid materials, to investigate correlation between TiO2 matrix and H3PW12O40. Phtocatalytic tests show the composite exhibits higher photocatalytic activity to decompose the Rhodamine B ( RhB ) than anatase TiO2.

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Advanced Materials Research (Volumes 610-613)

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68-71

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December 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. Fujishima, K. Honda, Nature. vol. 238 (1972), p.37

Google Scholar

[2] Hoffmann, M. R. Martin, S. T. Choi, W.Bahnemann, D. W. Chem. ReV. vol. 95(1995), p.69

Google Scholar

[3] K. Fukuda, Y. Being, T. Shibata, T. Aizawa, I. Nakai, J. Am. Chem. Soc. vol.129 (2007), p.202

Google Scholar

[4] G. Liu, L. Wang, H. Yang, H. Cheng, G. Lu, J. Mater. Chem. vol. 20 (2010), p.831

Google Scholar

[5] N. Mizuno, M. Misono, Chem. Rev. vol. 98(1998), p.199

Google Scholar

[6] I.V. Kozhevnikov, J. Mol. Catal. A. Chem. vol. 262 (2007), p.86

Google Scholar

[7] T. Tachikawa, M. Fujitsuka, T. Majima, J. Phys. Chem. C. vol. 111 (2007), p.5259

Google Scholar

[8] Jing. L. Q, Fu. H. G, Wang.B. Q, Wang, D. J, Xin, B. F, Appl. Catal. B . vol. 62 (2006), p.282

Google Scholar

[9] Kamat, P. V. Chem. ReV, vol. 93 (1993), p.267

Google Scholar

[10] Litter, M. I. Appl. Catal. B, vol. 23 (1999), p.89

Google Scholar

[11] Zhao. J. C, Wu.T. X, Wu. K. Q, Oikawa, N. Environ. Sci. Technol, vol. 32 (1998), p.2394

Google Scholar