Adsorption of Porous Imidazolium-Based Ionic Liquid Polymers: Effect of Swelling Conditions on CO2 Adsorptive Properties

Jia Mei Zhu; Kai Ge He; Feng Xin; Ya Chai Sun

doi:10.4028/www.scientific.net/AMR.616-618.1095

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 616-618Adsorption of Porous Imidazolium-Based Ionic...

Adsorption of Porous Imidazolium-Based Ionic Liquid Polymers: Effect of Swelling Conditions on CO₂ Adsorptive Properties

Abstract:

The seed-swelling method was adopted to synthesized the porous copolymer of 1-allyl-3-methylimidazolium tetrafluoroborate and acrylonitrile P([amim]BF4-AN). The samples were characterized by IR, DSC and CO₂ sorption was investigated by determining equilibrium data. The effects of the amount of initiator and swelling time on the porous structure and CO₂ sorption were discussed in detail. The results indicated that porous P([amim]BF4-AN) with benzoyl peroxide (BPO)0.1g and swelling 20h has the higher CO₂ sorption capacity.

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Periodical:

Advanced Materials Research (Volumes 616-618)

Pages:

1095-1098

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.616-618.1095

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Online since:

December 2012

Authors:

Jia Mei Zhu, Kai Ge He, Feng Xin, Ya Chai Sun

Keywords:

Ionic Liquid (IL), Porous Copolymer, Seed-Swelling

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