Effect of a Zwitterionic Copolymer on the Rheological Behavior of Aqueous α-Al2O3 Suspensions

You Qiang Chen; Xin Ni Zhang; Qing Shan Kong; Yan Zhi Xia

doi:10.4028/www.scientific.net/AMR.629.386

Paper Titles

Study on Carbonization Thermal Dynamic Process of Coal Tar Refined Soft Pitch
p.364

The Research of Second Acid Fracturing Temporary Plugging Agent in Long Interval Gas Well of Puguang
p.370

Formation of Methyl Acrylate from Methyl Acetate and Formaldehyde Condensation over Solid Base Catalysts
p.376

Effect of Steam Treatment on Catalytic Performance of La₂O₃-HZSM-5 for Methylation of Toluene with Methanol
p.381

Effect of a Zwitterionic Copolymer on the Rheological Behavior of Aqueous α-Al₂O₃ Suspensions
p.386

Effect of Crosslink on Properties of Thermoplastics Dialdehyde Sweet Potato Starch
p.391

Characterization of Nano Ni/MgO-ZrO₂ Catalysts
p.396

Moving Load and Fatigue Analysis of a Long Span High Speed Railway Bridge
p.403

Moving Loads Bridge Response: Structural Analysis and Eurocode Provisions
p.409

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 629Effect of a Zwitterionic Copolymer on the...

Effect of a Zwitterionic Copolymer on the Rheological Behavior of Aqueous α-Al₂O₃ Suspensions

Abstract:

A zwitterionic copolymer has been synthesized and a common optimum concentration of dispersant for the stabilized Al₂O₃ suspensions is found at 0.04wt%, which represents the adsorption saturation limit of polyelectrolytes at Al₂O₃ –water interface at pH = 10. Based on the results from rheological measurements, involving the effect of dispersant concentration, a stable broader dispersant concentration range of 0.4wt% ~ 0.22wt% is observed for suspensions with solids loading ≤ 50vol%, a stable broader pH range of 7.0 ~ 11.2 for suspension with solids loading ≤ 50vol%, and a stable pH range of 1.2 ~ 2.0 for suspensions with solids loading ≤ 40vol%.

You might also be interested in these eBooks

Material Sciences and Manufacturing Technology

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 629)

Pages:

386-390

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.629.386

Citation:

Cite this paper

Online since:

December 2012

Authors:

You Qiang Chen, Xin Ni Zhang, Qing Shan Kong, Yan Zhi Xia

Keywords:

Dispersant, Zeta-Potential, Zwitterionic Rheology, α-Al₂O₃

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] J. A. Lewis. Colloidal Processing of Ceramics.J. Am. Ceram. Soc. 2000; 83: 2341–59.

Google Scholar

[2] M. Montero, T. Molina, M. Szafran, R. Moreno and M. I. Nieto. Alumina porous nanomaterials obtained by colloidalprocessing using d-fructose as dispersant and porosity promoter. Ceram. Int. 2012; 38: 2779–84.

DOI: 10.1016/j.ceramint.2011.11.048

Google Scholar

[3] A. Natoli, A. Cabeza, Á. G. De La Torre, M. A. G. Aranda and I. Santacruz. Colloidal Processing of Macroporous TiO2 Materials for Photocatalytic Water Treatment. J. Am. Ceram. Soc. 2012: 95: 502–08.

DOI: 10.1111/j.1551-2916.2011.04883.x

Google Scholar

[4] D. Guo,K. Cai L.T. Li, and Z.L. Gui. Application of Gelcasting to the Fabrication of Piezoelectric Ceramic Parts, J. Eur. Ceram. 2003; 23: 1131-37.

DOI: 10.1016/s0955-2219(02)00279-0

Google Scholar

[5] R. Gilissen J.P. Erauw, and A. Smolders et al., Gelcasting, a near net shape technique, Mater Design, 2000; 21: 251-57.

DOI: 10.1016/s0261-3069(99)00075-8

Google Scholar

[6] J. Wang and L. Gao. Surface and electrokinetic properties of Y-TZP suspensions stabilized by polyelectrolytes, Ceram. Int., 2000; 26: 187-91.

DOI: 10.1016/s0272-8842(99)00038-3

Google Scholar

[7] Y. Hirata,S. Tabata, and J. Ideue. Interactions in the Silicon Carbide–Polyacrylic Acid–Yttrium Ion System, J. Am. Ceram. Soc, 2003; 86: 5.

DOI: 10.1111/j.1151-2916.2003.tb03269.x

Google Scholar

[8] J. Cesarano Ⅲ and I.A. Aksay. Processing of Highly Concentrated Aqueous α-Alumina Suspension Stabilized with Polyelectrolytes. J. Am. Ceram. Soc. 1988; 71: 1062-67.

DOI: 10.1111/j.1151-2916.1988.tb05792.x

Google Scholar

[9] J. Cesarano Ⅲ, I.A. Aksay, and A. Bleier. Stability of Aqueous α-Al2O3 Suspension with Poly(Methacrylic Acid) Polyelectrolyte. J. Am. Ceram. Soc. 1988; 71: 250-55.

DOI: 10.1111/j.1151-2916.1988.tb05855.x

Google Scholar

[10] C.G. de kruif. Hydrodynamics of Dispersed Media. Edited by J.P. Hulin, A.M. Cazab at, E. Guyon, and F. Carmona. Elsevier Science, Amsterdam, The Netherlands, 1990, pp.79-85.

Google Scholar