Synthesis of Polydiethyoxylsiloxane Catalyzed by Dehydrated Tetramethylammonium Hydroxide

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Abstract:

Tetramethylammonium hydroxide (TMAH) was dehydrated, and then used to catalyze the dimethyl cyclic siloxane ring cleavage and polymerize. The ethanol was used as both the solvent of TMAH and the capping agent to terminate the polymerization. Thus the high quality polydimethylsiloxane was synthesised. The influence of the amount of hexamethyl disiloxane was investigated. The investigation is of significant importance in both theoretical and practical aspects.

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80-83

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December 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] DU Zuo-dong. Organosilicon chemistry. Higher Education Press, Beijing, (1990).

Google Scholar

[2] YAN Hui, DIAO Yong. Development of Dimethyl Silicone Oil and its Derivatives in Defoamer Field. Fine and Specialty Chemicals, 2010, 18(1): 19-22.

Google Scholar

[3] ZHANG Guo-dong, LI Xiang-yang. Application of Silicone Materials in Cosmetics. Detergent and Cosmetics, 2006, 6(29): 29-31.

Google Scholar

[4] ZHAO Qian. Synthesis of Polydimethylsiloxane with Solid Super Acid SO42-/ZrO2-A12O3 asCatalyst. Guangdong Chemical Industry, 2008, 35, 45-48.

Google Scholar

[5] ZHAO Jian-hong, ZHAO Ming-xing, WANG Liu-cheng, SONG Cheng-ying, LIU Zhi-sheng, XU Hai-sheng. Synthesis of Polydimethylsiloxane with Solid Super Acid TiO2/SO42- as Catalyst. 2006, 14, 21-24.

Google Scholar

[6] XU Xiao-qiang, LIN Yan, FU Ren-jun. The synthesis of methyldiethoxysilane. Silicone material, 2006, 20, 67-69.

Google Scholar

[7] LIN Juan. Study on the Direct Synthesis of Triethoxysilane. Dissertation for the Master's Degree of Science, Harbin Institute of Technology, Harbin, (2007).

Google Scholar

[8] KONG Chui-hua. The novel method for the synthesis of low viscosity dimethyl siloxane. Chemistry World, 1989, (10), 447-449.

Google Scholar