Chemical Bonding Characteristics of Lanthanide Complexes: a Case of Valence Study

Huan Zhang; Xu Zhang; Jun Guo Ma

doi:10.4028/www.scientific.net/AMR.634-638.3

Paper Titles

Preface and Conference Organization

Chemical Bonding Characteristics of Lanthanide Complexes: a Case of Valence Study
p.3

Development of the Simulation Software on the Complex Reaction Kinetics
p.7

Energy-Level Splitting of Cs₂NaYCl₆ Crystal Doped with Praeseodymium
p.11

NBO Analysis the Chlorine Anion Recognition Mechanism of the Urea-Based Involving Iodine and Fluorine Derivation Functional Molecular Material
p.15

The Computer Simulation of the Acid-Base Titration
p.20

The Junction Width Effect on Inelastic Electron Tunneling Spectroscopy in Octanethiolate Molecular Junctions
p.25

The Orientation Effect on Inelastic Electron Tunneling Spectroscopy in Octanethiolate Molecular Junctions
p.29

The Geometry Structure and Molecular Vibrational Property of the Zeatin
p.33

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Chemical Bonding Characteristics of Lanthanide Complexes: a Case of Valence Study

Abstract:

A number of newly Ln-N bond valence parameters were quantitatively estimated, which allowed us to obtain all Ln-N bond lengths with different coordination numbers in metal organic complexes. Twenty linear correlations among the mean bond valence parameters of Ln-O, Ln-N, Ln-S, Ln-Cl and Ln-C bonds of metal organic complexes have been well established and denoted by a set of linearity equations, which provides us a useful method to determine the bond valence parameters of other type Ln-atom bonds in coordination chemistry. The present work shows us a novel approach to deeply understand the chemical bonding characteristics between Ln and the ligands in various metal organic complexes.