Study on Spectrophotometric Determining Trace Tetracycline by Phase-Separation Floatation

Abstract:

A novel and green method for separating and enriching trace tetracycline(TC) in environment water by phase-separation Floatation has been proposed,the principium was discussed. In this paper,the hydrophobic complex composed of Al(III) and TC was floated into organic phase under the optimal conditions: PH=6.2, the floatation equipment is home-made, The n-propyl alcohol is organic solvent ,sodium chloride is separating phase reagent.The data were obtained by spectrophotometry after floatation; The linear regression equation was A= 2.5759×105C (mol•L-1)－0.2716, The linear ranges were from 5×10-7 to 7.8×10-5 mol·L-1, respectively, with the correlation coefficient (r) better than r=0.9998, The average relative recoveries were 100.1% to 102.3% ,The limit of detection was 3.86×10-8mol·L-1 , It can be applied to analyse the trace TC in water sample ,the results were better.

• Periodical: Advanced Materials Research (Volumes 652-654)
• Pages: 1652-1655
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.652-654.1652
• Online since: January 2013
• Authors: Yan Min Hou, Jin Min Xie
• Keywords: Aluminium (III), Phase-Separation Floatation, Spectrophotometry, TC

References

[1] WU Gen-hua, WANG Jie, CHEN Jin-long. 　Spectroscopy and Spectral Analysis, 2008, 28(4): 913~916.

[2] LIU Bao-sheng, WANG Yun-ke , ZHANG Yan-qing. Spectroscopy and Spectral Analysis, 2008, 28(1): 153~155.

[3] Calamari D. Toxicology [M], 2002 , 181-182 : 183-186.

[4] YUE Zhen-feng, QIU Yue-ming, LIN Xiu-yun．Chinese Journal of Analytical Chemist ry, 2006, 34（10）: 1255～1259.

[5] ZHANG Lan, LIN Zi-an, XIE Zeng-hong．Analysis and Testing Technology and Instruments, 2004, l0(1): 1 8～23.

[6] RAO Zhi-ming, ZHOU Ping, CHEN Mei. Spectroscopy and Spectral Analysis, 2008, 28(2): 269~272.

[7] ZHANG Lan-wei, CHEN Yi, HAN Xue. Chinese Journal of Analytical Chemist ry , 2008, 36(7): 900~904.