Flame Retardant Low Density Polyethylene with Aluminium Hydroxide/ Commercial Fire Retardants FR01 Synergistic System

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Abstract:

Low density polyethylene (LDPE) was modified by the addition of commercial fire retardants FR01 and aluminium hydroxide (ATH). ATH/FR01/LDPE composites were prepared by melt blending and extrusion in a twin-screw extruder. ATH was first modified by a silane coupling agent KH550 then added to LDPE. The flame retardancy, electrical property and thermal behavior of the LDPE composites were investigated by limiting oxygen index (LOI), volume resistivity and thermogravimetric analysis (TGA), respectively. The results indicated that the surface modification of ATH (M-ATH) could greatly improve the dispersibility and compatibility with LDPE matrix. The mechanical property tests showed good mechanical properties of composite, compared with unmodified one, tensile strength and elongation of M-ATH/LDPE were all improved, and the addition of FR01 improved the flame retardancy of ATH/LDPE remarkably. TGA results demonstrate that char yield of M-ATH/FR01/LDPE (30/15/70) reaches 27 wt% at 600 °C in Ar atmosphere.

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Periodical:

Advanced Materials Research (Volumes 652-654)

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485-489

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Online since:

January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. A. Sener and E. Demirhan. The investigation of using magnesium hydroxide as a flame retardant in the cable material by cross-linked polyethylene. Mater. Design 29 (2008) 137-139.

DOI: 10.1016/j.matdes.2007.05.008

Google Scholar

[2] Y. Liu, et al. A novel intumescent flame-retardant LDPE system and its thermo-oxidative degradation and flame-retardant mechanisms. Polym. Adv. Technol. 19 (2008) 1566-1575.

DOI: 10.1002/pat.1171

Google Scholar

[3] H. S. Liu, X. L. Zhang and L. X. Song. Comprehensive Evaluation and Prediction of Fire Accidents in China Based on Statistics. China Safety Science Journal. 21 (2011) 54-59.

Google Scholar

[4] M. A. Bahattab, et al. Cross-linked poly(ethylene vinyl acetate) (EVA)/LDPE/metal hydroxides composites for wire and cable applications. Polym. Bull 64 (2010) 569-580.

DOI: 10.1007/s00289-009-0194-0

Google Scholar

[5] W. G. Cui, F. Guo and J. F. Chen. Preparation and properties of flame retardant high impact polystyrene. Fire Safety Journal. 42 (2007) 232–239.

DOI: 10.1016/j.firesaf.2006.11.002

Google Scholar

[6] X. G. Zhang. Investigation of interfacial modification for flame retardant ethylene vinyl acetate copolymer/alumina trihydrate nanocomposites. Polym. Degrad. Stabil. 87 (2005) 411-418.

DOI: 10.1016/j.polymdegradstab.2004.08.013

Google Scholar

[7] J. Z. Liang and Y. J. Zhang. A study of the flame-retardant properties of polypropylene /Al(OH)3/Mg(OH)2composites. Polym Int. 59 (2010) 539-542.

DOI: 10.1002/pi.2733

Google Scholar