The Study of a New Synthesis Method of Isoamyl Enol Polyoxyethylene Ether and its Compatibility on Cement

Article Preview

Abstract:

In this study, a kind of water reducing agent based on Isoamyl enol polyoxyethylene ether were synthesized in water solution by radical copolymerization. The influence of copolymerization conditions on dispersing performance of the water reducing agent in the cement was investigated. The molecular structure of the copolymer was tested by NMR, and GPC was used to determine the molecular weight of copolymer and the big monomer percent conversion, also, testing the adaptability of the water reducing agent in different types of cement. The testing results show that the water reducing agent has the good performance on concrete. When the dosage of water reducing agent was 0.2%, the (Deer ding card, P.O42.5) slurry flow degree of the cement was 270mm, and the water reducing ratio reached 19.6%. When the dosage of water reducing agent was 0.3% and 0.4%, the water reducing ratio reached to 28.6% and 31.9% respectively. Comparing the adaptability of the water reducing agent on all kinds of cement, the water reducing agent performed the worst in the P.C cement and better in the P.O cement, its adaptability in the standard cement and P.S cement was the best. When the dosage of water reducing agent was 0.2%-0.4%, the water reducing ratio was nearly the same, When the dosage of water reducing agent was 0.4%-0.6%, the water reducing ratio in the standard cement was higher than in the P.S cement.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

84-87

Citation:

Online since:

April 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Kinosita M,Yuki T.Methacrylic type water soluble polymer as high range water reducing agent for ultra high strength concrete. Japanese Journal of Polymer Science and Technology, 6(1995)357-363.

DOI: 10.1295/koron.52.357

Google Scholar

[2] Cyril Guérandel, Lionel Vernex-Loseta, Gabriel Kriera, Michel De Lanèveb,A new method to analyze copolymer based superplasticizer traces in cement leachates. Polym. Sci, 4(2011)133-140.

DOI: 10.1016/j.talanta.2010.12.022

Google Scholar

[3] Ran Qianping, Miao Changwen, Liu Jiaping.Performance andmechanism of a multi-functional superplasticizer for concrete, Materials Transactions, 6(2006)1599-1604.

DOI: 10.2320/matertrans.47.1599

Google Scholar