Extraction of Tantalum from Ta2O5 Using SOM Process

Article Preview

Abstract:

A novel process of solid-oxide-oxygen-ion conducting membrane (SOM) technique has been investigated to produce Ta metal directly from Ta2O5 in molten CaCl2. The sintered porous Ta2O5 pellet was employed as the cathode while liquid copper, saturated with graphite powder and encased in a one-end-closed yttria-stabilized-zirconia (YSZ) tube, acted as the anode. The particle sizes and porosity of the cathode pellets are important factors that have significant impact on the electrolysis process. The optimal experimental conditions is pellet sintering and electrolytic temperature 1100°C, cell voltage 3.5V, electrolysis time 2h.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 690-693)

Pages:

25-29

Citation:

Online since:

May 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] F. Cardarelli, P. Taxil, A. Savall, J. Appl. Electrochem. Vol. 28 (1998).p.245

Google Scholar

[2] L. Massot, P. Chamelot, P. Palau, P. Taxil,Electrochimica Acta, Vol.50 (2005) .p.5408

DOI: 10.1016/j.electacta.2005.03.021

Google Scholar

[3] M. Baba, Y. Ono, R.O. Suzuki, J. Phy and Chem,Vol.66 (2005) .p.466

Google Scholar

[4] M.A. Hunter, J. Metals. Vol.5 (1953) 130-132.

Google Scholar

[5] A. Krishnan, X.G.Lu and U. B. Pal, J.Scan. Metall. Vol.34(2005) .p.1

Google Scholar

[6] G. Z. Chen, D. J. Fray, T. W. Farthing, Nature.Vol.407(2000) .p.361

Google Scholar

[7] G. Z. Chen, E. Gordo, D. J. Fray, Metall. Mater. Trans. B35 (2004) .p.223

Google Scholar

[8] U.B. Pal, A .Krishnan, X.G. Lu, JOM, Vol.56(2004) .p.245

Google Scholar

[9] D.T.L. Alexander, C. Schwandt , D.J. Fray,Acta Materialia. Vol. 54 (2006) .p.2933

Google Scholar