Innovative Utilization of a Borate Additive in Magnesium Production to Decrease Environmental Impact of Fluorides from Pidgeon Process

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Abstract:

The present authors have utilized, for the first time, H3BO3 as an additive in pilot scale experiments of Mg production using Pidgeon process. The results from the experiments revealed positive effects of H3BO3 on both quantity and quality of the Mg metal crowns. Besides acting as a catalyzer for MgO reduction, H3BO3 stabilized also β-Ca2SiO4 in the Mg slag. Based on these results, H3BO3 may be adopted as an innovative additive replacing fluorite in the Mg production, to enhance sustainability and environmental soundness for the Pidgeon process in China.

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Advanced Materials Research (Volumes 690-693)

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378-389

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May 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Editorial Column, The yearbook of nonferrous metals industry of China 2005 [M]. Beijing, China Nonferrous Metals Industry Association (2005), p.503 (in Chinese)

Google Scholar

[2] Hongxiang LIU et al.: Light Metals, 11, (2010), 43 (in Chinese)

Google Scholar

[3] Jindan Du et al.: Journal of Cleaner Production, 18, (2010), 112

Google Scholar

[4] Pidgeon LM, Alexander WA: in New York Meeting: reduction and refining of non-ferrous metals, Trans Am Inst Mining Mater Eng 159 (1944), p.315

Google Scholar

[5] Toguri JM, Pidgeon LM: Can J Chem., 40 (1962), p.1769

Google Scholar

[6] Zang JC: In: Hryn J, editor. Magnesium technology Proceedings of the Minerals, Metals and Materials Society Meeting 01, New Orleans, Louisiana, 11–15 February (2001), p.7

Google Scholar

[7] MA Hongwen, et al.: GEOSCIENCE, Vol 22, No. 5 (2008) p.829 (in Chinese)

Google Scholar

[8] Feng GAO, Zuo-ren NIE et al: Trans. Nonferrous Met. Soc. China 18 (2008), p.749

Google Scholar

[9] Feng GAO, Zuo-ren NIE et al: Int J Life Cycle Assess (2009) 14, p.480

Google Scholar

[10] RAMAKRISHNAN S et al.: [J]. Resources Conservation & Recycling, 24, (2004), p.49

Google Scholar

[11] Laner Wu et al.: in Proceedings of International Conference on Solid Waste Technology and Management, Mar. 11-14, (2012), Philadelphia, USA

Google Scholar

[12] Han, F. et al.: Advanced Materials Research; Nr 577 (2012) p.31, Trans Tech Publications, Switzerlan

Google Scholar

[13] Congyun Huang et al.: Cement Guide for New Epoch, No. 5 (2005) p.27 (in Chinese)

Google Scholar

[14] Han, F. et al.: Advanced Materials Research Vols. 418-4 (2012) p.1657, Trans Tech Publications, Switzerland

Google Scholar

[15] Han, F. et al.: Advanced Materials Research; Nr 581–582 (2012) p.1044, Trans Tech Publications, Switzerland

Google Scholar

[16] Final draft prEN 12457-2, Characterization of waste-Leaching-Compliance test of leaching of granular waste material and sludges

DOI: 10.3403/bsen12457

Google Scholar

[17] Official Journal of the European Communities pursuant to Article 16 of and Annex II to Directive 1999/31/EC, 16.1.(2003)

Google Scholar

[18] Mikael Persson et al.: ISIJ International, Vol. 47, No. 12 (2007) p.1711

Google Scholar

[19] Ryo INOUE et al: ISIJ International, Vol. 42, No. 7, (2002), p.785

Google Scholar

[20] Hideo MIZUKAMI et al.: ISIJ International, Vol. 44, No. 3, (2004), p.623

Google Scholar

[21] Hideaki SUITO et al: ISIJ International, Vol. 42, No. 8 (2002), p.921

Google Scholar

[22] A.B. Fox et al.: ISIJ International, Vol. 45, No. 7 (2005), p.1051

Google Scholar

[23] Hongming WANG et al.: ISIJ International, Vol. 51, No. 5 (2010), p.702

Google Scholar

[24] Peng Liu et al.: Materials Chemistry and Physics 79 (2003) 270

Google Scholar

[25] Eung Soo Kim et al.: Material Science and Engineering, B99, (2003) 243

Google Scholar

[26] Cheng-Liang Huang et al.: Journal of Alloys and Compounds 461 (2008) 440

Google Scholar

[27] Ching-Fang Tseng et al.: Journal of Alloys and Compounds, 491 (2010), p.314

Google Scholar

[28] Qixing Yang et al.: in Proceedings of The 7th Nordic-Japan Symposium on Science and Technology of Process Metallurgy, Jernkontoret, Stockholm, September 15-16, (2005)

Google Scholar

[29] Qixing Yang et al.: in Proceedings of The Iron & Steel Technology Conference, AISTech 06, May 1-4, 2006, Cleveland, Ohio, USA. Volume 1, p.573

Google Scholar

[30] Y.-L. Chen et al.: Journal of Hazardous Materials 170 (2009) 443

Google Scholar