For Libraries For Publication Open Access Downloads About Us Contact Us
Paper Titles
A Comparative Study of UHMWPE Multifilament and Aramid Multifilament
p.84
The Influence of Introduction of Polyethylene Glycol on Synthesis of Bimodal Mesoporous γ-Al2O3
p.89
Study on Preparation of Ni/C Composite Powder by Electroless Plating Compound Complex Agent
p.93
Avoidance Test for the Assessment of Microbial Degradation of PAHs
p.98
MeAPO4 Berlinite as an Effective Catalyst for Mild Oxidation of Cyclohexane
p.102
Mechanism of the Oxidation of Iron
p.106
Synthesis of Viscosity-Variable Diverting-Acid Main Agent and Diverting Performance Evaluation
p.110
High-Density Li0.95Na0.05FePO4 Cathode Material Synthesized by Co-Precipitation and Microwave Heating
p.117
Effects of Processing on Fiber Distribution and Mechanical Performance of Engineered Cementitious Composites (ECC)
p.122

MeAPO4 Berlinite as an Effective Catalyst for Mild Oxidation of Cyclohexane

Article Preview

Abstract:

Cobalt and/or manganese incorporated berlinites (CoMnAPO4) and aluminophosphate molecule sieve (CoMnAPO-5) were hydrothermally synthesized, characterized by XRD, FT-IR, XPS and SEM, and employed as catalysts in the oxidation of cyclohexane with molecular oxygen at 348 K under atmospheric pressure. It was found that the berlinite-based catalysts were more selective for the production of KA oil, stable during the reaction, but slightly less active for the conversion of cyclohexane, when compared to their molecular sieve counterparts. The CoMnAPO4 exhibited a better catalytic performance, due to a synergic effect, than the CoAPO4 or MnAPO4.

You might also be interested in these eBooks
Advances in Applied Science, Engineering and Technology View Preview

Info:

Periodical:

Advanced Materials Research (Volume 709)

Pages:

102-105

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.709.102

Citation:

Cite this paper

Online since:

June 2013

Authors:

Da Lei Sun, Zi Sheng Chao

Keywords:

Berlinite, Cyclohexane, Oxidation

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

References

[1] K. Weissermel, H.J. Arpe, Industrial Organic Chemistry, 2nd Edition, VCH Press, Weiheim, 1993. pp.281-304.

Google Scholar

[2] J.M. Thomas, R. Raja, G. Sankar, Acc. Chem. Res. 34 (2001) 191-200.

Google Scholar

[3] B.P.C. Hereijgers, B.M. Weckhuysen, J. Catal. 270(2010)16-25.

Google Scholar

[4] M. Rokita, M. Handke, W. Mozgawa, J. Mol. Struct. 450 (1998) 213.

Google Scholar

[5] M. Vippola, J. Vuorinen, P. Vuoristo, T. Lepisto, T. Mantyla, J. Eur. Ceram. Soc. 22 (2002) 1937.

Google Scholar

[6] M. Vippola, S. Ahmaniemi, J. Keranen, et al. Olsson, Mater. Sci. Eng., A 323 (2002) 1.

Google Scholar

[7] D.M. Christie, N. Troullier, J.R. Chelikowsky, Solid State Commun. 98(10) (1996) 923.

Google Scholar

[8] A.N. Sreeram, L.W. Hobbs, N. Bordes, et al. Methods Phys. Res., Sect. B 116 (1996) 126.

Google Scholar

[9] J.D. Chen, R.A. Sheldon, J. Catal. 153 (1995) 1.

Google Scholar

[10] B. Modén, B.Z. Zhan, J. Dakka, et al. J. Catal. 239 (2006) 390.

Google Scholar

[11] J.B. Parise, Inorg. Chem. 24 (1985) 4312-4316.

Google Scholar

[12] D.L. Sun, J.R. Deng, Z.S. Chao, Chemistry Central Joural, 1 (2007) 27-35.

Google Scholar

[13] R.A. Sheldon, I.W.C.E. Arends, H.E.B. Lempers, Catal. Today 41 (1998) 387-407.

Google Scholar

© 2025 Trans Tech Publications Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. For open access content, terms of the Creative Commons licensing CC-BY are applied.
Scientific.Net is a registered trademark of Trans Tech Publications Ltd.