Study of Biosorption of Rare Earth Metals (La, Nd, Eu, Gd) by Sargassum sp. Biomass in Batch Systems: Physicochemical Evaluation of Kinetics and Adsorption Models

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This work evaluated kinetic and adsorption physicochemical models for the biosorption process of lanthanum, neodymium, europium, and gadolinium by Sargassum sp. in batch systems. The results showed: (a) the pseudo-second order kinetic model was the best approximation for the experimental data with the metal adsorption initial velocity parameter in 0.042-0.055 mmol.g-1.min-1 (La < Nd < Gd < Eu); (b) the Langmuir adsorption model presented adequate correlation with maximum metal uptake at 0.60-0.70 mmol g-1 (Eu < La < Gd < Nd) and the metal-biomass affinity parameter showed distinct values (Gd < Nd < Eu < La: 183.1, 192.5, 678.3, and 837.3 L g-1, respectively); and (c) preliminarily, the kinetics and adsorption evaluation did not reveal a well-defined metal selectivity behavior for the RE biosorption in Sargassum sp., but they indicate a possible partition among RE studied.

Info:

Periodical:

Advanced Materials Research (Volumes 71-73)

Edited by:

Edgardo R. Donati, Marisa R. Viera, Eduardo L. Tavani, María A. Giaveno, Teresa L. Lavalle, Patricia A. Chiacchiarini

Pages:

605-608

DOI:

10.4028/www.scientific.net/AMR.71-73.605

Citation:

R.C. Oliveira and O. Garcia Jr., "Study of Biosorption of Rare Earth Metals (La, Nd, Eu, Gd) by Sargassum sp. Biomass in Batch Systems: Physicochemical Evaluation of Kinetics and Adsorption Models", Advanced Materials Research, Vols. 71-73, pp. 605-608, 2009

Online since:

May 2009

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$35.00

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