Effect of Surface Oxidation at 1500 °C on Flexural Strength and Thermal Shock Resistance of the ZrB2-SiC-ZrC Ceramic

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Abstract:

The isothermal oxidation of the ZrB2-SiC-ZrC ceramic was carried out in static air at a constant temperature of 1500±15 oC for 20 min. Compared with the original strength of 580 MPa, the strength of the oxidized specimen increased to 655±45 MPa, because the flaws in the surface of the specimen were sealed by the oxide layer. The thermal shock resistance of the specimens before and after the oxidation was measured by the water quenching. The measured ΔTcrit for the oxidized specimen was 641 oC that was obviously greater than 348 °C for the unoxidized specimen. The improvement in the thermal shock resistance was attributed to the formation the oxide layer on the surface of the specimen. The results here pointed to a promising method for improving strength and thermal shock resistance of ZrB2-based ceramics.

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Periodical:

Advanced Materials Research (Volumes 712-715)

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115-118

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June 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] J.C. Han, P. Hu, X.H. Zhang, S.H. Meng, W.B. Han, Oxidation-resistant ZrB2-SiC composites at 2200°C, Compos. Sci. Technol. 68 (2008) 799-06.

DOI: 10.1016/j.compscitech.2007.08.017

Google Scholar

[2] F Monteverde, Progress in the fabrication of ultra-high-temperature ceramics: "in situ" synthesis, microstructure and properties of a reactive hot-pressed HfB2-SiC composite, Compos. Sci. Technol. 65 (2005) 1869-79.

DOI: 10.1016/j.compscitech.2005.04.003

Google Scholar

[3] C.M. Chen, L.T. Zhang, W.C. Zhou, Z.Z. Hao, Y.J. Jiang, S.L. Yang, Microstructure, mechanical performance and oxidation mechanism of boride in situ composites, Compos. Sci. Technol. 61 (2001) 971-75.

DOI: 10.1016/s0266-3538(00)00187-1

Google Scholar

[4] S.K. Mishra, S.K. Das, V. Sherbacov, Fabrication of Al2O3-ZrB2 in situ composite by SHS dynamic compaction: A novel approach. Compos. Sci. Technol. 67 (2007) 2447-53.

DOI: 10.1016/j.compscitech.2006.12.017

Google Scholar

[5] W.D. Kingery, Factors affecting thermal stress resistance of ceramic materials, J. Am. Ceram. Soc. 38[1] (1955) 3-15.

Google Scholar

[6] J.W. Zimmermann, G.E. Hilmas, W.G. Fahrenholtz, Thermal shock resistance of ZrB2 and ZrB2-30%SiC, Mater. Chem. Phys. 112 (2008) 140-45.

DOI: 10.1016/j.matchemphys.2008.05.048

Google Scholar

[7] W.M. Guo, G.J. Zhang, Y.M. Kan, P.L. Wang, Oxidation of ZrB2 powder in the temperature range of 650-800 °C, J. Alloys Compd. 471 (2009) 502-06.

DOI: 10.1016/j.jallcom.2008.04.006

Google Scholar