Solid Super Acid Base Co-Catalyzed Transesterification of Soybean Oil Using Ultrasonication

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Abstract:

Biodiesel is a renewable, biodegradable, and nontoxic fuel. At present, biodiesel is primarily produced in batch reactors in which the required energy is provided by heating accompanied by mechanical mixing. Alternatively, ultrasonic processing is an effective way to attain required mixing while providing the necessary activation energy. Biodiesel was synthesized by soybean oil using ultrasonication and alkali-acid catalysis method. Its structure was characterized by gas chromatograph, and the effects of various factors on transesterification rate were studied. The results show that a biodiesel yield in excess of 98% can be achieved in 30 min, methanol/oil molar ratio of 6:1, alkali-acid catalysis includes 0.5% of NaOH and 0.5% of solid super acid.

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Periodical:

Advanced Materials Research (Volumes 724-725)

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419-422

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August 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Ma, F.; Hanna, M. A. Biodiesel production: A review. Bioresour. Technol. 1999, 70, 1-15.

Google Scholar

[2] Schuchardt, U.; Sercheli, R.; Vargas, R. M. A review. J. Braz. Chem. Soc. 1998, 9 (1), 199-210.

Google Scholar

[3] Benitez, F. A. University of Puerto Rico,Mayaguez, Puerto Rico, 2004.

Google Scholar

[4] Stavarache, C.; Vinatoru, M.; Nishimura, Chem. Lett. 2003, 32 (8), 716-717.

Google Scholar

[5] Stavarache, C.; Vinatoru, M.; Nishimura, R.; Maeda, Y. Fatty acids methyl esters from vegetable oil by means of ultrasonic energy. Ultrason. Sonochem. 2005, 12 (5), 367-372.

DOI: 10.1016/j.ultsonch.2004.04.001

Google Scholar

[6] Shah, S.; Sharma, A.; Gupta, M. N. Extraction of oil from Jatrophe curcas L. seed kernels by combination of ultrasonication and aqueous enzymatic oil extraction. Bioresour. Technol. 2005, 96, 121-123.

DOI: 10.1016/j.biortech.2004.02.026

Google Scholar

[7] Fu, B. S., Gao, L. J., Niu, L., Wei, R. P., Xiao, G. M., Biodiesel from waste cooking oil via heterogeneous superacid catalyst. Energy Fuel 2009, 23, 569–572.

DOI: 10.1021/ef800751z

Google Scholar

[8] Li, Y., Zhang, X. D., Sun, L., Zhang, J., Xu, H. P., Fatty acid methyl ester synthesis catalyzed by solid superacid catalyst. Appl. Energy 2010, 87, 56–159.

DOI: 10.1016/j.apenergy.2009.06.030

Google Scholar

[9] Zullaikah, S., Lai, C. C., Vali, S. R., Ju, Y. H., A two-step acid-catalyzed process for the production of biodiesel from rice bran oil. Bioresour. Technol. 2005, 96, 1889–1896.

DOI: 10.1016/j.biortech.2005.01.028

Google Scholar