Synthesis of Mixed TiO2-Rare Earth Up-Conversion Material and Application in the Dye-Sensitized Solar Cells

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Abstract:

Rare earth ion-doped nanoparticles NaYF4:Yb3+,Ho3+ is one of the most efficient up-conversion nanosystems, when mixing a TiO2 heterogeneous layer outside can extends the range of NaYF4:Yb3+,Ho3+ nanoparticles absorb solar energy. In this work, a multi-functional mixed NaYF4:Yb3+,Ho3+-TiO2 structure was synthesized. The micromorphology, structure and particle size of the up-converting nanoparticles were characterized by transmission electron microscopy (TEM), and room temperature up-conversion luminescence (UCL) spectrofluorimetric measurements. The mixture of NaYF4:Yb3+,Ho3+ and TiO2 nanoparticles was applied to Dye-sensitized solar cells (DSSCs), the photoelectric conversion efficiency of the DSSC with up-conversion material is nearly twice as much as of the control DSSC irradiated by infrared (IR) light.

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Periodical:

Advanced Materials Research (Volumes 724-725)

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89-92

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August 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] T.W. Hamann, R.A. Jensen, A.B.F. Martinson, H.V. Ryswyk and J.T. Hupp: Energy Environ. Sci. Vol. 1(2008), p.66

Google Scholar

[2] A.B. O'Regan and M. Grätzel: Nature Vol. 353 (1991), p.737

Google Scholar

[3] Y.J. Sun, Y. Chen, L.J. Tian, Y. Yu, X.G. Kong, J.W. Zhao and H. Zhang: Nanotechnology Vol. 18 (2007), p.275609

Google Scholar

[4] I. Pastoriza-Santos, D.S. Koktysh, A.A. Mamedov, M. Giersig, N.A. Kotov and L.M. Liz-Marzán: Langmuir Vol. 16(2000), p.2731

DOI: 10.1021/la991212g

Google Scholar

[5] H.X. Mai, Y.W. Zhang, L.D. Sun and C.H. Yan: J. Phys. Chem. C Vol. 111 (2007), p.13730

Google Scholar

[6] Z.Q. Ai, G.L. Sun, Q.L. Zhou and C.S. Xie: J. Appl. Polym. Sci. Vol. 102 (2006) , p.1466

Google Scholar

[7] C.H. Qi , C.X. Liu, F.Y. Lin et al. Chinese J. Lasers Vol. 25 (1998) , p.561

Google Scholar