A New and Sensitive Hydride Generation-Nanosilver Resonance Rayleigh Scattering Spectral Method for Trace Se (IV)

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Abstract:

In HCl solution, the Se (IV) was reduced to SeH2 by NaBH4, and absorbed by solution of ethanol-AgNO3. The Ag+ was reduced to nanosilver, which led to the resonance Rayleigh scattering (RRS) peak at 366 nm increased. Under the selected conditions, the RRS intensity at 366 nm was linear to the concentration of Se (IV) in the range of 0.05-2.0 μg/mL, a detection limit of 0.02 μg/mL. The proposed method was applied to detect Se (IV) in water samples, with satisfactory results.

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Advanced Materials Research (Volumes 734-737)

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2456-2459

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August 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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