Effects of Propargyl Alcohol on Electrochemical Behaviors of AZ91 Magnesium Alloy Anode in 3.5% NaCl Solution

Article Preview

Abstract:

To improve corrosion rates and activation properties of AZ91 magnesium alloy anode, effects of additives (propargyl alcohol) on electrochemical behaviors of AZ91 magnesium alloy in 3.5% NaCl solution have been examined by studying corrosion rate, polarization, open circuit potential (Eocp) and transfer resistance values (Rt) of electrochemical impedance spectroscopy(EIS). The results show that propargyl alcohol not only decreases corrosion rate of AZ91 magnesium alloy anode, corrosion-inhibition ratio is 64.6%, but also increases activation properties of AZ91 when 1.0 % propargyl alcohol added into 3.5% NaCl solution. The current density of AZ91 reaches 9.46 mA.cm-2 at-1.35V. Its active potential (Eact ) is-1.527 V , and Eocp is-1.556 V.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 750-752)

Pages:

1137-1140

Citation:

Online since:

August 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] R. Udhayan and P.B. Devendra: J Power Sources, Vol. 63 (1996), p.103.

Google Scholar

[2] Y.F. Yao, C.G. Chen, Y.P. Liu and R. Wang: Materials Review, Vol. 23, No. 10 (2009), p.119.

Google Scholar

[3] Y. Li, G.L. Song, et al: Corrosion Science and Protection Technology, Vol. 11 (1999), p.202.

Google Scholar

[4] G. Song, A. Atrens and D. Stjohn: Corrosion Science, Vol. 39 (1997), p.855.

Google Scholar

[5] G. Song, A. Atrens, X. Wu and B. Zhang: Corrosion Science, Vol. 40 (1998), p.1769.

Google Scholar

[6] H.B. Shao, J.M. Wang and Z. Zhang: Materials Chemistry and Physics, Vol. 77 (2002), p.305.

Google Scholar

[7] H.C. Lin: Corrosion Science and Protection Technology, Vol. 9, No. 4 (1997), p.308.

Google Scholar

[8] H.H. Li, Y.T. Zhao and X.P. Guo: Corrosion & Protection, Vol. 28, No. 3 (2007), p.113.

Google Scholar

[9] Q.B. Tan, H.G. Yang and X.M. Zhu: J Dalian Jiaotong University, Vol. 29, No. 1 (2008), P. 89.

Google Scholar