Synthesis, Characterization, Optical and Electrochemical Properties of Multinuclear Cobaltadithiolene Complex Derivatives

Yao Fang Zhao; Jing Hua An; Xiao Min Kang; Ya Nan Wu; Bao Hua Zhu

doi:10.4028/www.scientific.net/AMR.750-752.1795

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 750-752Synthesis, Characterization, Optical and...

Synthesis, Characterization, Optical and Electrochemical Properties of Multinuclear Cobaltadithiolene Complex Derivatives

Abstract:

Four new multinuclear cobaltadithiolene complex derivatives [Cp*CoFe₂(CO)₆(η², μ₃-S₂C₆H₂(SC₃H₇)₂)] 1, [Fe (CpPPh₂)₂(Cp*CoS₂C₆H₂(SC₃H₇)₂)₂] 2, [Cp*CoRu (CO)₃(CH₂=CHCH₂) (η²,μ₂-S₂C₆H₂(SC₃H₇)₂)] 3 and [Cp*Co (NSO₂C₆H₄CH₃)(S₂C₆H₂(SC₃H₇)₂)] 4 were obtained by reaction of mono-nuclear cobaltadithiolene complex [Cp*CoS₂C₆H₂(SC₃H₇)₂] (Cp*=C₅(CH₃)₅) with Fe₃(CO)₁₂, Fe (CpPPh₂)₂ (1,1'-bis (diphenylphosphino) ferrocene), Ru (CO)₃(CH₂=CHCH₂)Br, C₆H₅I= NSO₂C₆H₄CH_3(p) (N-(Phenyliodonio)-p-toluene sulfonamidate), respectively. All new complexes were characterized by C/H analysis, ¹H NMR, MS and IR spectroscopy. Furthermore, the optical and electrochemical properties of some complexes were also determined by UV-Vis spectra and cyclic voltammogram (CV) analysis.

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Advanced Materials Research (Volumes 750-752)

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1795-1798

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https://doi.org/10.4028/www.scientific.net/AMR.750-752.1795

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August 2013

Authors:

Yao Fang Zhao, Jing Hua An, Xiao Min Kang, Ya Nan Wu, Bao Hua Zhu

Keywords:

Addition Reaction, Cobaltadithiolene Complex, Multinuclear Metal Cluster, Property

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