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Liquid-Phase Oxidation of Toluene to Benzoic Acid over Manganese Oxide Catalyst

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Abstract:

Manganese oxide (Mn3O4) catalyst was prepared by decomposition method and characterized by X-ray powder diffraction (XRD) and fourier transform infrared spectrum (FTIR). Catalytic activity of Mn3O4 was tested by the oxidation of toluene to benzoic acid with molecular oxygen in liquid-phase and solvent free conditions. As a result, 45% conversion of toluene and 91% selectivity of benzoic acid was achieved. It is proved that Mn3O4 catalyst can use several runs without decrease of activity.

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Periodical:

Advanced Materials Research (Volumes 750-752)

Pages:

1822-1825

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.750-752.1822

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Online since:

August 2013

Authors:

Xiao Qiang Li*, Long Fei Yang

Keywords:

Catalysis, Liquid, Manganese Oxide, Oxidation, Toluene

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] J. A. Labinger, J. E. Bercaw: Nature, Vol. 417(2002), p.507.

Google Scholar

[2] C. Jia, T. Kitamura, Y. Fujiwara: Acc. Chem. Res., Vol. 34(2001), p.633.

Google Scholar

[3] T. Morimoto and Y. Ogata.: J. Chem. Soc. (B), Phys. Org. Vol. 12(1967), p.1353.

Google Scholar

[4] A. Palermo, J. P. H. Vazquez, and R. M. Lambert: Catalysis Letters, Vol. 68(2000), p.191.

Google Scholar

[5] M. I. Zaki, M. A. Hasan, L. Pasupulety et al: Thermochimica Acta Vol. 311(1998), p.97.

Google Scholar

[6] G. Marban, T. Valdes-Solis, and A. B. Fuertes: Journal of Catalysis Vol. 1(2004), p.138.

Google Scholar

[7] S. Rabiei, D. E. Miser, J. A. Lipscomb et al.: Journal of Materials Science, Vol. 40(2005), p.4995.

Google Scholar

[8] X. Chen, Y. F. Shen, S. L. Suib et al.: J. Catal. Vol. 197(2001), p.292.

Google Scholar

[9] G. Marba'n, Teresa Valde's-Solı's, Antonio B. Fuertes: Phys. Chem. Chem. Phys., Vol. 6(2004) p.453.

Google Scholar

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