Dual-Frequency Ultrasonic Desorption of Pb2+ from Coconut Shell Activated Carbon

Article Preview

Abstract:

Desorption experiments of coconut shell activated carbon (CSAC) saturated with Pb2+ had been conducted in presence of dual-frequency and single-frequency (30 kHz,500 kHz,1200 kHz) ultrasound. The desorption efficiency was better at dual-frequency ultrasound than at single-frequency ultrasound. The best of desorption efficiency of Pb2+ was 65.5% at 500×500 kHz. The desorption efficiency of Pb2+ increased by increasing temperature, but when the temperature was more than 50°C, the desorption efficiency decreased initially. The stability of CSAC was not affected with cavitation effect produced by ultrasound of frequency of 500×500 kHz. The carbon loss was less. The rate of loss was only 0.6%. In conclusion, ultrasound was used as alternative method to regenerate activated carbon adsorbing with heavy metal ion.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

38-42

Citation:

Online since:

September 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] A. D. Meintyre, Ecological Toxicology research effects of heavy metal and Organohalogen Compounds. Plenum Press, NewYork, (1975).

Google Scholar

[2] Guohua Jing, Meixia Dong, Zuoming Zhou, Effects of ultrasound on adsorption and desorption of chromium(Ⅵ) on activated carbon, CIESC Journal. 60(2009) 2806-2812.

Google Scholar

[3] L. Monser, N. Adhoum. Modified activated carbon for the removal of copper, zinc, chromium and cyanide from waste water, Separation and Purification Technology. 26(2002)137-146.

DOI: 10.1016/s1383-5866(01)00155-1

Google Scholar

[4] C. Gabaldn, P. Marzal, J. Ferrer, et al. Single and competitive adsorption of Cd and Zn onto a granular activated carbon, J. Water Research, 30(1996)3050-3060.

DOI: 10.1016/s0043-1354(96)00165-0

Google Scholar

[5] M.H. Entezari, T.R. Bastami, Sono-sorption as a new method for the removal of leadion from aqueous solution, Journal of Hazardous Materials. 137(2006)959-964.

DOI: 10.1016/j.jhazmat.2006.03.019

Google Scholar

[6] C. Moreno-Castilla, J. Rivera-Utrilla, J.P. Joly. et al. Thermal regeneration of an activated carbon exhausted with different substituted phenols, Carbon. 33 (1995) 1417–1423.

DOI: 10.1016/0008-6223(95)00090-z

Google Scholar

[7] J.E. Kilduff, C.J. King, Effect of carbon adsorbent surface properties on the uptake and solvent regeneration of phenol, Ind. Eng. Chem. Res. 36(1997)1603.

DOI: 10.1021/ie960545v

Google Scholar

[8] H. Zhang. Regeneration of exhausted activated carbon by electrochemical method, Chem. Eng. J. 85 (2002) 81–85.

Google Scholar

[9] Y. Nakano, L.Q. Hua, W. Nishijima, M. Okada, Biodegradation of trichloroethylene (TCE)adsorbed on granular activated carbon (GAC), Water Res. 34(2000)4139.

DOI: 10.1016/s0043-1354(00)00199-8

Google Scholar

[10] Jae-Lim Lim, Mitsumasa Okada. Regeneration of granular activated carbon using ultrasound[J], Ultrasounds Sonochemistry, 12(2005), 277-282.

DOI: 10.1016/j.ultsonch.2004.02.003

Google Scholar

[11] Sanfan Wang, Preliminary study on ultrasound regeneration of activiated carbon, China Water & Wastewater. 14(1998)24-26.

Google Scholar

[12] S.U. Rege, R.T. Yang, C.A. Cain, Desorption by ultrasound: phenol on activated carbon and polymeric resin, AIChE J. 44 (1998)1519–1528.

DOI: 10.1002/aic.690440706

Google Scholar

[13] T.J. Mason, Practical Sonochemistry: User's guide to applications in chemistry and chemical engineering, Ellis Horwood, Chichester, 1991, 186.

Google Scholar

[14] O. Hamdaoui, E. Naffrechoux, L. Tifouti, C. Petrier, Effects of ultrasound on adsorption-desorption of p-chlorophenol on granular activated carbon, Ultrason Sonochem. 10(2003)109-114.

DOI: 10.1016/s1350-4177(02)00137-2

Google Scholar

[15] L.H. Thompson, L.K. Doraiswamy, Sonochemistry: science and engineering, Ind. Eng. Chem. Res. 38 (1999) 1215–1249.

DOI: 10.1021/ie9804172

Google Scholar