Hydrothermal Synthesis and Crystal Structure of a Cobalt Complex

Liang Jun Gao; Wen Dong Song

doi:10.4028/www.scientific.net/AMR.781-784.571

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 781-784Hydrothermal Synthesis and Crystal Structure of a...

Hydrothermal Synthesis and Crystal Structure of a Cobalt Complex

Abstract:

A new coordination polymer based on cobalt nitrate and 2-4-pyridyl-1H-benzimidazole- 5,6-dicarboxylate (H₂pbd), namely [Co (pbd)₂·(H₂O)₂]_n·n (H₂O)₂, have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. The crystal of the complex crystallizes in triclinic, space group P-1 with a=7.6708(6)Å, b=8.0009(8)Å, c=12.8348(12)Å, α=96.4040(10) o, β=102.9480(10) o, γ=112.142(2) o, V=694.11(11)Å³, Z=1, C₂₈H₂₂CoN₆O₁₂ and F(000)=376.0. The H₂pbd ligand links the Co (II) atoms into a double stranded chain.

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Advanced Materials Research (Volumes 781-784)

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571-575

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.781-784.571

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Online since:

September 2013

Authors:

Liang Jun Gao, Wen Dong Song

Keywords:

2-4-Pyridyl-1H-Benzimidazole-5, 6-Dicarboxylate, Cobalt (II) Complex, Hydrothermal Synthesis

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