Preparation and Application of Lead Dioxide Electrode for Zinc Electrolysis

Article Preview

Abstract:

According to the process of anodic oxygen evolution in sulfate system for zinc electrolysis,Ti-base lead dioxide electrode can be prepared to use in this case.The surface characterization of the electrode was studied by Scanning electron microscopy(SEM) and X-ray diffraction(XRD).The electrode lifetime was tested in 1mol/L H2SO4 solution at 60°C,and the electro-catalytic properties was examined by polarization curves.Then these samples was enlarged and simulation test was conducted at Mengzi marriage zinc smelter in Yunnan.The results show that the electro-catalytic properties is better and the electrodes lifetime is longer compared to the traditional lead electrode.Moreover,it has a significant effect in reducing energy consumption, manufacturing cost and improving the production and grade of zinc.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 785-786)

Pages:

1125-1129

Citation:

Online since:

September 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J.Y. Chen: Hydrometallurgical Manual(Metallurgical Industry Press, China, 2005).

Google Scholar

[2] S. Trasatti: Electrochim Acta. Vol. 29 (1984) No. 11, p.1503.

Google Scholar

[3] F.K. Ma: Rare metals Manual(Metallurgical Industry Press, China, 2008).

Google Scholar

[4] Team of plating manual: Plating Manual(National Defense Industry Press, China, 1980).

Google Scholar

[5] A. Felder and R.D. Prengaman: JOM. Vol. 58 (2006) No. 10, pp.28-31.

Google Scholar

[6] I. Ivanov: Hydrometallurgy, Vol. 72 (2004) No. 1, pp.73-78.

Google Scholar

[7] Z.Z. Zhang G.E. Zhao and X.J. Luo: Introduction of Titanium Electrode(Metallurgical Industry Press, China, 2008).

Google Scholar

[8] H.M. Mefny and W. S Abdel: Electrochem Acta. Vol. 41 (1996) No. 9, p.1419.

Google Scholar

[9] D. Pavlov and B.J. Monahov: Electrochem Soc. Vol. 143 (1996) No. 11, p.3616.

Google Scholar

[10] H.B. Beer: J Electrochem Soc. Vol. 127 (1980) No. 8, pp.303-308.

Google Scholar

[11] C.C. Chang and T.C. Wen: J Appl Electrochem. Vol. 27 (1997) No. 3, pp.355-363.

Google Scholar

[12] H.L. Hu and N. Li: Electrochemical Measurement(National Defense Industry Press, China, 2007).

Google Scholar

[13] I. Chiaki,I. Meguru and M. Masatsugu: Electrochimica Acta. Vol. 48 (1980) No. 2, pp.91-96.

Google Scholar

[14] U. Schumann,P. Grundle: Wat Rs. Vol. 32 (1998) No. 9, 2835-2842.

Google Scholar