The Study on Curing Kinetics of Lignin Based Epoxy Resin System Using Non-Isothermal DSC Method

Ming Qiang Chen; Shao Min Liu; Feng Li; Zhong Lian Yang; Ye Zhang

doi:10.4028/www.scientific.net/AMR.788.223

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 788The Study on Curing Kinetics of Lignin Based Epoxy...

The Study on Curing Kinetics of Lignin Based Epoxy Resin System Using Non-Isothermal DSC Method

Abstract:

The synthesis of Lignin Base Epoxy Resin was based on industrial alkali lignin, and lignin-based epoxy resin curing characteristics were analyzed using the thermal weight loss technology under the oxygen atmosphere conditions. In light of the infra-red analysis of raw materials, the curing reaction kinetic parameters of lignin-based epoxy resin system were calculated using the Kissinger-Crane and Flynn-Wall-Ozawa method, and the curing reaction kinetics model of lignin-based epoxy resin system was established. The results showed that the kinetic parameters obtained using two methods were approximate, which validated that the curing reaction was consistent with the principle of the first-order reaction model. Initial curing temperature T_i0=454.88 K, curing temperature T_p0=507.55 K, and terminal temperature T_f0=598.77 K of lignin-based epoxy resin system were obtained when the extrapolation method was applied.

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Periodical:

Advanced Materials Research (Volume 788)

Pages:

223-227

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.788.223

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Online since:

September 2013

Authors:

Ming Qiang Chen, Shao Min Liu, Feng Li, Zhong Lian Yang, Ye Zhang

Keywords:

Curing, DSC Curve, Kinetics Model, Lignin-Based Epoxy Resin

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