Corrosion Inhibitor Performance with Presence of FeCO3 Film in CO2 Corrosion Environment under Fluid Flow Effect

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Corrosion due to carbon dioxide (CO2) has a major impact on the oil and gas industry by severely affecting production and process facilities. One of the most economic methods to prevent the corrosion of piping and plants is the application of corrosion inhibitors. The presences of corrosion product such as iron carbonate (FeCO3) film may affect to the performance of corrosion inhibitor. In addition to that, fluid flow effect in pipeline may also influence the performance of corrosion inhibitor. Thus, the present work is conducted to study the effect of FeCO3 film to the performance of imidazoline based corrosion inhibitor under fluid flow effect. The experiments were done in glass cells at 80°C. The hydrodynamic condition experiment was simulated using rotating cylinder electrode (RCE). Corrosion inhibitor was added at two different concentrations in the iron carbonate film formation. A corrosion rates were measured by linear polarization resistance (LPR) method. The film was later analyzed using scanning electron microscopy (SEM). It was found that a better corrosion protection is still offered by corrosion inhibitor even with presence of FeCO3 film. A synergistic effect is offered by these two films of corrosion inhibitor and FeCO in reducing corrosion rate.

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507-510

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Nesic, et al., "Testing of inhibitors for carbon dioxide corrosion using the electrochemical techniques," in Proceedings of the 8th European ymposium on corrosion inhibitors, Ann. Univ. Ferrara, 1995, p.1163.

Google Scholar

[2] H. Malik, "Influence of C16 quarternary amine on surface films and polarization resistance of mild steel in carbon dioxide saturated 5% sodium chloride," Corrosion Engineering Science and Technology, vol. 51, p.321, 1995.

DOI: 10.5006/1.3293597

Google Scholar

[3] K. D. Efird, "Jet impingement testing for flow accelerated corrosion," Corrosion/1990, NACE International, Houstan, Texas, paper no. 00052, 2000.

Google Scholar

[4] A. Y. Musa, et al., "Stability of layer forming for corrosion inhibitor on mild steel surface under hydrodynamic conditions," Int. J. Electrochem. Sci., vol. 4, pp.707-716, 2009.

Google Scholar

[5] S. Nesic, "Acid gas corrosion of mild steel," Corrosion and Multiphase Technology, Ohio University, Athens.

Google Scholar

[6] R. H. Hausler and G. Schmitt, "Hydrodynamic and flow effects on corrosion inhibiton," Reviews on Corrosion Inhibitor Science and Technology, vol.3, Edited by A. Rahman, P. Labine, and M.A. Quraishi, NACE, 2004.

Google Scholar

[7] L.D. Paolinelli, T. Perez and S.N. Simison, ''The effect of pre-corrosion and steel microstructure on inhibitor performance in CO2 corrosion, " Corrosion Science, vol. 50, pp.2456-2464,2008.

DOI: 10.1016/j.corsci.2008.06.031

Google Scholar