Void Content Determination of Fiber Reinforced Polymers by Acid Digestion Method

Abstract:

Porosity of the fiber-reinforced polymer (FRP) is one of very important quality characteristics for the advanced use of the material in order to ensure full performance properties are attained. It was found that the porosity values of FRP in typical aircraft composite parts must be lower than 2.5 % to achieve the required mechanical properties. The most common method for measuring the void content is through acid digestion testing or burn-off method, since it provides the true values that could be used to generate the database properties of the materials. Thus, this paper discussed the detail of the acid digestion test procedures for the void content measurement of FRP, especially with regards to the suitable testing time and chemical volumetric quantity required to ensure the matrix of test sample has been completely extracted. In order to attain this, different test samples for different processing techniques were prepared. Subsequently, the findings were discussed within the context of void content in cured monolithic composite for different types of process, in which the samples from the VBO-oven curing process were compared with those of the autoclave-cured samples. In the VBO-oven curing process, the use of an intensifier during the curing provided higher void content of 15.52% in comparison with those achieved through the debulking process (10.91%). It has been clearly observed that the debulking produced a substantial effect towards the air evacuation mechanism within the laminate.

• Periodical: Advanced Materials Research (Volume 795)
• Pages: 64-68
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.795.64
• Online since: September 2013
• Authors: M Hafiz Hassan, Abdul Rahim Othman, S. Kamaruddin
• Keywords: Acid Digestion Testing, Aircraft Composite Parts, Out-of-Autoclave, Void Contents

References

[1] W. Michaeli, F.J. Vossebürger, H. Greif and L. Wolters, Technologie der Kunststoffe, München: Carl Hanser Verlag (2003).

[2] E.A. Birt and R.A. Smith, A review of NDE methods for porosity measurement in fibre reinforced polymer composites. Insight 46 (11) (2004) 681-686.

DOI: 10.1784/insi.46.11.681.52280

[3] J. Schuller and R. Oster, Classification of porosity by ultrasonic in carbon fibre helicopter structures based on micro computed tomography, Proceedings European conference on nondestructive testing, Berlin, Germany September (2006) 25–29.

[4] J.W. Park, D.J. Kim, K.H. Im, S.K. Park, D.K. Hsu, A.H. Kite, S.K. Kim, K.S. Lee and I.Y Yang, Ultrasonic influence of porosity level on CFRP composite laminates using Rayleigh probe waves. Acta mechanica solida sinica 21(4) (2008) 298-307.

DOI: 10.1007/s10338-008-0834-1

[5] L. Lin, M. Luo, H.T Tian, X.M Li and G.P. Guo, Experimental investigation on porosity of carbon fibre-reinforced composite using ultrasonic attenuation coefficient. Proceedings World Conference on Nondestructive Testing, Shanghai, China, October (2008) 25.–28.

[6] I.M. Daniel, S.C. Wooh and I. Komsky, Quantitative porosity characterization of composite materials by means of ultrasonic attenuation measurements. Journal of nondestructive evaluation 11(1) (1992)1-12.

DOI: 10.1007/bf00566012

[7] ASTM D 3171-99 Standard Test Method for Constituent Content of Composite Materials.

[8] P. Green, Fibre volume fraction determination of carbon-epoxy composites using an acid digestion bomb. Journal of materials science letters Vol. 10, (1991) 1162-1164.

DOI: 10.1007/bf00744114

[9] L. Liu, B.M. Zhang, D.F. Wang and Z.J. Wu, Effects of cure cycles on void content and mechanical properties of composite laminates. Journal of Composite Structures, 73(3)(2006) 303-309.

DOI: 10.1016/j.compstruct.2005.02.001

[10] K.J. Bowles and S. Frimpong,Void effects on the interlaminar shear strength of composite laminates. Journal of Composite Structures, 31(2)(1997)1487-1509.

DOI: 10.1177/002199839202601006

[11] S.R. Ghiorse, Effect of void content on the mechanical properties of carbon/epoxy laminates. SAMPE QUARTERLY Vol. 1, (1993) 54-59.