Preparation and Friction Performance of the Nano Ag-APS Single Molecular Self-Assembled Film

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Abstract:

The Ag nanoparticles was prepared by reduction of silver nitrate with sodium citrate, and the APS monolayers was self-assembled with 3-Aminopropyltrimethoxysilane (APS) on the monocrystalline silicon surface. Then, Ag/APS molecular self-assembled film was formed with Ag nanoparticles and APS membrane by liquid method. The chemical structure and morphology of the Ag nanoparticles and self-assembled film were investigated by AFM, XRS and IR. Meanwhile, the friction performances of self-assembled film was also investigated. The results shown that the Ag nanoparticle have the morphology of spherical particles with an average particle size of ca. 65 nm in diameter which were successful assembled on the surface of APS film and partially oxidized into Ag2O. The friction coefficient of the Ag-APS molecular self-assembled film has been decreased with the assembled time extened while the wear rate has improved.

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351-355

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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DOI: 10.1021/ma001489j

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