Thermochemical Properties of Dissolution of Nitroguanidine in Dimethyl Sulfoxide and N,N-Dimethylformamide

Abstract:

Abatract. The enthalpies of dissolution for nitroguanidine (NQ) in dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF) were measured using a RD496-2000 Calvet microcalorimeter at 298.15 K. Empirical formula for the calculation of the enthalpies of dissolution (Δ_dissH) was obtained from the experimental data of the dissolution processes of NQ in DMSO and DMF. The corresponding kinetic equations describing the dissolution processes were dα/dt=10^-1.49(1-α)^0.94 for the dissolution of NQ in DMSO and dα/dt=10^-1.59(1-α)^0.90 for the dissolution of NQ in DMF.

• Periodical: Advanced Materials Research (Volume 800)
• Pages: 417-423
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.800.417
• Online since: September 2013
• Authors: Li Bai Xiao, Xiao Ling Xing, Feng Qi Zhao, Hong Xu Gao, Li Na, Luo Yang, Jian Hua Yi
• Keywords: Dimethyl Sulfoxide, Dissolution, Kinetic, N,N-Dimethylformamide, Nitroguanidine

References

[1] N.Q. Li, Z.B. Zhang, The study on a new kind of nitroguanidine propellant, Chinese Journal Explosives ﹠ Propellants. (2001)34-35.

[2] C.Z. Du, Y. Yan, Studies on effect of NGu ignition property of nitramine propellant, Chinese. J. Explosives ﹠ Propellants. 27(2001)52-54.

[3] Z.Z. Zhang, S.J. Jiang, Burning behavior of nitramine propellant under low pressure, Chinese journal of Energetic Materials. 15(2007)125-127.

[4] R. L. Trask, S. Samuel, I. G. Nadel, U.S. Patent, 3086896 (1963).

[5] R.K. Murmann, R. Glaser, C. L Barnes. Structures of nitroso and nitroguanidine X-ray crystallography and computational analysis, Journal of chemical Crystallography. 35(2005) 317-325.

DOI: 10.1007/s10870-005-3252-y

[6] C.W. Fong, R.C. Warren, An Interphasic Region between Nitrocellulose and Nitroguanidine in triple base propellant energetic materials, Propellants, Explosives, Pyrotechnics. 10(1985)69-72.

DOI: 10.1002/prep.19850100304

[7] V.K. Marthada, The enthalpy of solution of SRM 1655(KCl) in H2O, Res. Natl. Bur. Stand. 85(1980)467.

DOI: 10.6028/jres.085.027

[8] R. Sabbah, A.X. Wu, J.S. Chickos, M.L.P. Leitão, M.V. Roux, L.A. Torres, Reference materials for calorimetry and differential thermal analysis. Thermochim. Acta. 331(1999)93.

DOI: 10.1016/s0040-6031(99)00009-x

[9] L.B. Xiao, L.X. Xiao, Z.X. Fan, F.Q. Zhao, M.Z. Zhi, H.F. Huang, T. An, H. X. Hao, Q. Pei, Thermochemical properties of di(N, N-di(2, 4, 6-trinitrophenyl)amino)-ethylenediamine in dimethyl sulfoxide and N-methyl pyrrolidone, J. Therm. Anal. Calorim. 110(2012).

DOI: 10.1007/s10973-011-2036-1

[10] L.B. Xiao, F.Q. Zhao, L.X. Xiao, H.F. Huang, M.Z. Zhi, T. An, Q. Pei, Y. Tan, Dissolution properties of ammonium dipicrylamide in dimethyl sulfoxide and N-methyl pyrrolidone, Thermochim. Acta. 546(2012)138-140.

DOI: 10.1016/j.tca.2012.07.003

[11] X.L. Xing, L. Xue, F.Q. Zhao, H.X. Gao, R.Z. Hu, Dissolution properties of 1, 1-diamino-2, 2-didinitrorthylene (FOX-7) in dimethyl sulfoxide (DMSO). Thermochim Acta. 32 (2009) 53–56.

DOI: 10.1016/j.tca.2009.02.019

[12] L.B. Xiao, L.X. Xiao, F.Q. Zhao, K.Z. Xu, E. G Yao, Y. Tan, H.X. Hao, Dissolution properties of 2-(Dinitromethylene)-5-methyl-1, 3-diazacyclopentane in dimethyl sulfoxide and N-methyl pyrrolidone, Chem. Res. Chinese Universities. 28(2012)743-744.

[13] X.L. Xing, L. Xue, F.Q. Zhao, J.H. Yi, H.X. Gao, S.Y. Xu, Q. Pei, H.X. Hao, Hu R.Z., Dissolution properties of the CL-20 in ethyl acetate and acetone. J. Therm. Anal. Calorim. 99(2010)703–705.

[14] F.Q. Zhao, L. Xue, X.L. Xing, R.Z. Hu, Z.M. Zhou, H.X. Gao, J.H. Yi, S.Y. Xu, Q. Pei, Thermochemical properties and thermokinetic behavior of energetic triazole ionic salts. Scientia Sin Chim. 40(2010)1430–1443.

DOI: 10.1007/s11426-010-4219-1

[15] L. Xue, F.Q. Zhao, X.L. Xing, H.X. Gao, S.Y. Xu, R.Z. Hu, Dissolution properties of 1, 3, 3-trinitroazetidine (TNAZ) in ethyl acetate and N, N-dimethylformamide. Acta. Phys. Chim. Sin. 25(2009)2413–2416.

[16] H.X. Gao, F.Q. Zhao, R.Z. Hu, Differential and integral isoconversional non-linear methods and their application to energetic materials. Chin. J. Chem. 26(2008)1973–(1977).

DOI: 10.1002/cjoc.200890353

[17] L. Xue, F.Q. Zhao, X.L. Xing, Z.M. Zhou, K. Wang, S.Y. Xu, H.X. Gao, J.H. Yi, R.Z. Hu, Thermal behavior of 3, 4, 5-triamino-1, 2, 4-triazole dinitramide. J. Therm. Anal. Calorim. 102( 2010)145–147.

DOI: 10.1007/s10973-010-0752-6

[18] F.Q. Zhao, S.Y. Heng, R.Z. Hu, H.X. Gao, F. Han. A study of kinetic behaviours of the effective centralite/stabilizer consumption reaction of propellants using a multi-temperature artificial accelerated aging test. J Hazard Mater. 145(2007)45–50.

DOI: 10.1016/j.jhazmat.2006.10.085

[19] J.H. Yi, F.Q. Zhao, S.Y. Xu, L.Y. Zhang, X.N. Ren, H.X. Gao, R.Z. Hu, Effect of pressures on decomposition reaction kinetics of double-base propellant catalyzed with cerium citrate. J. Therm. Anal. Calorim. 92(2009)318–321.

DOI: 10.1007/s10973-008-9241-6