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Metal Impurities Removal from Metallurgical Grade Silicon by Hydrochloric Acid Leaching
Abstract:
As a pre-treatment process for producing solar-grade silicon, hydrometallurgical method could remove the most of metallic impurities of metallurgical-grade silicon, which is a hopeful technology to provide solar energy material independence of the Siemens skill. Factors such as the hydrochloric mass fraction, temperature, reaction time, and particle size of silicon powders were investigated in the impurities removal experiments under the condition of mechanical stirring. The leached samples were analyzed by ICP and SEM. The optimum parameters, hydrochloric mass fraction 5%, temperature 80°C, reaction time 9h, particle size 75μm, were determined by single factor experiments and orthogonal experiments. The 86.1% of Fe, 68.1% of Al, 85.9% of Ca and 25.9% of B impurity was removed from metallurgical-grade silicon powder.
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7-10
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September 2013
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© 2013 Trans Tech Publications Ltd. All Rights Reserved
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