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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 821-822Structure – Property Relationships for Dyes of...

Structure – Property Relationships for Dyes of Different Nature

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Abstract:

Systematic analysis of quantitative structure – property relationships for dyes of different nature has been reviewed. On the basis of the experimental results published in the literature and theoretical evaluation of amphiphilic and electrophilic properties of dyes of different nature several basic conclusions of scientific and practical importance are proposed. It was found that water/octanol partition coefficients exhibit correlation with dye partition between hydrophobic synthetic fibres and dyebath as well as dye affinity. Hydrophobicity of dyes controls several technical properties of dyes and dyeings, such as wash fastness and light fastness, migration factor, rate of dyeing and fixation rate. Energy of frontier electronic orbitals (HOMO and LUMO energies) correlates with different properties characterizing redox properties of dyes: oxidative and reductive destruction in chemical reactions, photochemical and biochemical destruction of dyes, wash and light fastness of dyeings. The results of this study are useful for physico-chemical analysis of dye sorption by textile fibres, destruction of dyes in polymers and solutions as well as for design of new dyes of high quality.

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Advances in Textile Engineering and Materials III

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Periodical:

Advanced Materials Research (Volumes 821-822)

Pages:

488-492

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.821-822.488

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Online since:

September 2013

Authors:

Felix Telegin, Irina Shushina, Jian Hua Ran, Yulia Biba, Aleksandr Mikhaylov, Viktoriia Priazhnikova

Keywords:

Acid Dyes, Biodegradation, Chemical Degradation, Direct Dyes, Disperse Dye, Light Fastness, Photocatalytic Degradation, Reactive Dyes, Structure – Property Relationship, Vat Dyes, Wash Fastness

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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