Recovery of Precious Metals from Catalytic Converters of Automobiles by Hydrometallurgical Solid-Liquid Extraction Processes

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Today, among the basic requirements to be fulfilled by an automobile, those relating to environmental protection and recyclability are of great importance. This paper aims to present a new technological solution to recover rare metals - Platinum, Palladium and Rhodium - from automotive used catalysts, based on hydrometallurgical method of solid-liquid extraction. Following the theoretical and experimental researches, were established the technological sequences which must be carried for recovering precious metals from used automotive catalysts, in the pilot phase. The proposed technology has been applied for a quantity of 10 kg of used automotive catalysts of ceramic monolithic type, at the end of the recovery process and selective separation, resulting the following recovery efficiencies: 95 % for Platinum, 95 % for Palladium and 92 % for Rhodium. Finally, there were highlighted the main advantages of hydrometallurgical processes: versatility, economicity, high efficiencies and relatively low costs.

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105-109

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November 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] H. Tanakaa, M. Uenishia, M. Taniguchia, I. Tana, K. Naritab, M. Kimurab, K. Kanekoc, Y. Nishihatad, J. Mizukid, The intelligent catalyst having the self-regenerative function of Pd, Rh and Pt for automotive emissions control, Catalysis Today, Vol. 117 (2006).

DOI: 10.1016/j.cattod.2006.05.029

Google Scholar

[2] A. Fornalczyk, M. Saternus, Removal of platinum group metals from the used auto catalytic converter, Metabk 48(2), ISSN 0543-5846 (2009), 133-136.

Google Scholar

[3] A. Miuţescu, Contributions to Optimize Quality Maintenance of De-pollution Catalytic Equipments of Spark Ignition Engine and to Recover Precious Metals from Catalytic Converter Components, PhD Thesis, Piteşti, România, (2011).

Google Scholar

[4] M. Stoianovici, M., D. Brojboiu, Procedeu de recuperare şi separare selectivă a platinei, paladiului şi rodiului, din catalizatorii auto uzaţi, Brevet nr. 119128, România, (2004).

Google Scholar

[5] M.A. Barakat, G.A. El-Mahdy, M. Hegazy, F. Zahran, Hydrometallurgical recovery of nano-palladium from spent catalyst, The Open Mineral Processing Journal, 2 (2009) 31-36.

DOI: 10.2174/1874841400902010031

Google Scholar

[6] S. Steinlechner, J. Antrekowitsch, PGM Recycling from Catalysts in a Closed Hydrometallurgical Loop with an Optional Cerium Recovery, in REWAS 2013: Enabling Materials Resource Sustainability, John Wiley & Sons, Inc., Hoboken, NJ, USA, (2013).

DOI: 10.1002/9781118679401.ch39

Google Scholar