Effect of Rare Earth for Removal of Carbonyl Sulfide from Synthesis Gas

Article Preview

Abstract:

Fe-Mn metal oxides nanosized particles have been prepared by doping with La. The effects of promoters on the oxides were investigated by XRD, BET and other methods. XRD results revealed that the degree of crystallinity and particle size of mixed oxide phase decreased due to doping with La2O3. Addition of La led to a progressive increase in the surface area of the sample. Tests showed that the addition of 3 wt % La2O3 greatly improved the absorption sulfur capacity of the sorbent for COS removal. Keywords: Hydrogen utilized; Carbonyl Sulfide; Doping; La2O3

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 860-863)

Pages:

1017-1020

Citation:

Online since:

December 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Ruth, LA., Vision 21: Fossil fuel-based energy for the 21st century. Proceeding of workshop on clean energy utilization technology, Seoul, Korea; (2001).

Google Scholar

[2] Eiji Sasaoka, Tomoo Ichio and Shigeaki Kasaoka. High-Temperature H2S Removal from Coal-Derived Gas by Iron ore. Energy & Fuels 1992, 6, 603-608.

DOI: 10.1021/ef00035a010

Google Scholar

[3] B. Peter Williamsa, Nicola C. Younga, John Westb, Colin Rhodesb, Graham J. Hutchingsb, C.N. Satterfield, Carbonyl sulphide hydrolysis using alumina catalysts Heterogeneous Catalysis in Industrial Practice, McGraw-Hill, New York, 1991, p.378.

Google Scholar

[4] Federal Energy Technology Center. Vision 21 program plan: clean energy plants for the 21th century. FETC office of Fossil Energy, US Department of Energy; (1999).

DOI: 10.2172/766729

Google Scholar

[5] Lee A.L. Internal Reforming Development for Solid Oxide fuel Cells-Final Report; Department of Energy Report MC/220045-2364; U.S. Government Printing Offece: Washington, DC, (1987).

Google Scholar

[6] Kazuo Taniguchi,Md. Azhar Uddin, Shigeru Hirano,et al., Characterization of Reaction between ZnO and COS [J]. Eng. Chem. Res. 1996,35:2389-2394.

DOI: 10.1021/ie950370+

Google Scholar