Preparation of Phosphorus Modified HZSM-5 Zeolite Catalysts and their Catalytic Performances of Methanol to Olefins

Shu Xun Tian; Sheng Fu Ji; Qi Sun

doi:10.4028/www.scientific.net/AMR.875-877.295

Paper Titles

Exchange Bias Properties in Bulk Ni₄₅Co₅Mn₃₈Sn₁₂ Heusler Alloy
p.272

The Phase Structure and Electrochemical Properties of La₄MgNi_19-xCo_x(x=0～2) Hydrogen Storage Alloys
p.277

The Phase Structure and Electrochemical Properties of La₄MgNi₁₇M₂(M=Ni,Co,Mn) Hydrogen Storage Alloys
p.282

Development of Epoxy Composite Filled with Micro Tungsten Disulphide Particles and its Mechanical Properties
p.288

Preparation of Phosphorus Modified HZSM-5 Zeolite Catalysts and their Catalytic Performances of Methanol to Olefins
p.295

Affection of Post-Nitrogen-Doping of TiO₂ Nanoparticle Film Photo-Anode on Performance of Dye-Sensitized Solar Cells
p.300

Preparation, Characterization and Catalytic Activity of Highly Dispersed Gold Catalyst
p.304

Composition of the Middle Phase Microemulsion Formed by Sodium Dodecyl Sulfonate/1-Alcohol/n-Alkane/Water
p.308

A New Route for the Synthesis of Pure Bi₄(SiO₄)₃ Crystals by Glass Melt-Cooling Method
p.313

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 875-877Preparation of Phosphorus Modified HZSM-5 Zeolite...

Preparation of Phosphorus Modified HZSM-5 Zeolite Catalysts and their Catalytic Performances of Methanol to Olefins

Abstract:

To improve the selectivity of light olefins, Phosphorous modified ZSM-5 zeolites catalysts with different phosphorous content were prepared by impregnation and were used in the conversion of methanol to olefins. The properties of acidity and microporous structure of the phosphorous modified ZSM-5 zeolites were investigated by XRD, N₂-adsorption and desorption, and NH₃-TPD. The highest propylene yield (50.82%) was observed over the H-ZSM-5 modified with the phosphorus content at 9% (weight percent). The selectivity of propylene depended strongly on the phosphorus content in the zeolites; The enhancement of propylene selectivity with increasing phosphorous content was attributed to reduction of strong acid sites on the H-ZSM-5. Modification of the ZSM-5 zeolites with phosphorous also changes the microporous structure.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 875-877)

Pages:

295-299

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.875-877.295

Citation:

Cite this paper

Online since:

February 2014

Authors:

Shu Xun Tian, Sheng Fu Ji, Qi Sun

Keywords:

Modification, MTO, Phosphorous, Zeolite, ZSM-5

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] G.L. Zhao, J.W. Teng, Z.K. Xie, W.Q. Jin, W.M. Yang, Q.L. Chen and Y. Tang: J. Catal Vol. 248 (2007), p.29.

Google Scholar

[2] C.S. Mei, P.Y. Wen, Z.C. Liu, H.X. Liu, Y.D. Wang, W.M. Yang, Z.K. Xie, W.M. Hua and Z. Gao: J Catal Vol. 258 (2008), p.243.

Google Scholar

[3] M. Stöcker: Micro. Meso. Mater Vol. 29 (1999), p.3.

Google Scholar

[4] Y. Wei, D. Zhang, Z. Liu and B. Su: Chin. J. Catal (Cuihua Xuebao) Vol. 33 (2012), p.11.

Google Scholar

[5] L. Travalloni, A.L. Gomes, A.B. Gaspar and M.A. Silva: Catal. Today Vol. 133-135 (2008), p.406.

Google Scholar

[6] J.Q. Chen, A. Bozzano, B. Glover, T. Fuglerud and S. Kvisle: Catal. Today Vol. 106 (2005) p.103.

Google Scholar

[7] A. Jacobs. U.S. Patent 38, 945, 931. (1974).

Google Scholar

[8] M. BjØrgen, S. Svelle, F. Joensen, J. Nerlov, S. Kolboe, F. Bonino, L. Palumbo, S. Bordiga and U. Olsbye: J. Catal Vol. 249 (2007), p.195.

DOI: 10.1016/j.jcat.2007.04.006

Google Scholar

[9] W.J. Dehertog and G.F. Froment: Appl. Catal Vol. 71 (1991), p.153.

Google Scholar

[10] G.F. Froment W.J. Dehertog and A.J. Marchi: Catal. Commun. Vol. 9 (1992), p.1.

Google Scholar

[11] N. Xue, X. Chen, L. Nie, X. Guo, W. Ding, Y. Chen, M. Gu and Z. Xie: J. Catal Vol. 248 (2007), p.20.

Google Scholar

[12] J.Q. Zhuang, D. Ma, G. Yang, Z.M. Yan, X.M. Liu, X.C. Liu, X.W. Han, X.H. Bao, P. Xie and Z.M. Liu: J. Catal Vol. 228 (2004), p.234.

Google Scholar

[13] G.L. Zhao, J.W. Teng, Z.K. Xie, W.Q. Jin, W.M. Yang, Q.L. Chen and Y. Tang: J. Catal Vol. 248 (2007), p.29.

Google Scholar

[14] R.L. Cordero, F.J. Liamrias, J.M. Palacios, J.L. Fierro and A.L. Agudo: Appl. Catal Vol. 56 (1989), p.197.

Google Scholar