Synthesizes and Properties of 1-[2-methyl-5-(4-methoxyphenyl)-3-thieny-2-[2-methyl-5-(3-methoxy-4-formyphenyl)-3-thienyl] perfluorocyclopentene

Fang Duan; Xue Li; Gang Liu; Shou Zhi Pu

doi:10.4028/www.scientific.net/AMR.886.147

Paper Titles

Characteristics of Deposition Precipitation Process in Production of High Strength and Low Carbon Steel in FTSR
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Mechanical Reliability of Oxidized Zircaloy-4 Alloy Nuclear Cladding Tube in Compression
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Synthesis and Photochromism Studies of 1-(2-methyl-3-benzothiophene)-2-[2-methyl-5-(4-aminomethanephenyl)-3-thienyl]perfluorocyclopentene
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Synthesizes and Properties of 1-[2-methyl-5-(4-methoxyphenyl)-3-thieny-2-[2-methyl-5-(3-methoxy-4-formyphenyl)-3-thienyl] perfluorocyclopentene
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Synthesis and Properties of [1-(2-Methyl-5-pheyl-3-thienyl)-2-(2-methyl-5-(4-cyanophenyl)-3-thienyl]perfluorocyclopentene for Fluorescence Switch
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Synthesis and Properties of 1-[2,5-dimethyl-3-thienyl]-2-[2-methyl-5-(p-N,N-dimethylaminophenyl)-3-thienyl]perfluorocyclopentene
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Efficient Synthesis and Properties of a Photochromic Hybrid Diarylethene Bearing a Pyrimidine Moiety
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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 886Synthesizes and Properties of...

Synthesizes and Properties of 1-[2-methyl-5-(4-methoxyphenyl)-3-thieny-2-[2-methyl-5-(3-methoxy-4-formyphenyl)-3-thienyl] perfluorocyclopentene

Abstract:

A new unsymmetrical photochromic diarylethene compound, namely 1-[2-methyl-5-(4-methoxyphenyl)-3-thieny-2-[2-methyl-5-(3-methoxy-4-formyphenyl)-3-thieny perfluorocyclopentene, was synthesized and its properties were investigated in detail, including photochromic reactivity kinetics and concentration effect. The results showed that the compound exhibited remarkable photochromism, changing between colorless and blue in solution, respectively. What is more, the kinetic experiments illustrated that the cyclization/cycloreversion process of this compound was determined to be the zeroth/first reaction.

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Periodical:

Advanced Materials Research (Volume 886)

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147-150

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.886.147

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Online since:

January 2014

Authors:

Fang Duan, Xue Li, Gang Liu*, Shou Zhi Pu

Keywords:

Fluorescence, Kinetic, Unsymmetrical Diarylethene

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