Hard Template Route for Synthesis of Mesoporous Spinel Type Oxides with Ordered Structure

Wei Hua Shen

doi:10.4028/www.scientific.net/AMR.886.200

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 886Hard Template Route for Synthesis of Mesoporous...

Hard Template Route for Synthesis of Mesoporous Spinel Type Oxides with Ordered Structure

Abstract:

The binary mesoporous spinel oxides with high surface area have been synthesized by using KIT-6 and SBA-15 as hard templates and hydrated nitrated salts as precursors. Low temperature such as 500 °C is suitable for preparation of NiCo₂O₄ with spinel phase. High temperature such as 800 °C is necessary for preparation of NiMn₂O₄, MnCo₂O₄, and (Co_0.5Mn_0.5)₃O₄ with pure spinel phase. The prepared mesoporous spinel shows high surface area as 43-105 m²/g with pore volume as0.095-0.233 cm³/g. It is preferred to form mesoporous NiCo₂O₄ with spherical particles.

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Periodical:

Advanced Materials Research (Volume 886)

Pages:

200-203

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.886.200

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Online since:

January 2014

Authors:

Wei Hua Shen

Keywords:

Hard Template, Mesoporous Silica, Mesoporous Spinel, Metal Oxide

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References

[1] F. Jiao, A. Harrison, J.C. Jumas, A.V. Chadwick, W. Kockelmann and P.G. Bruce: J. Am. Chem. Soc. Vol. 128 (2006), p.5468.

Google Scholar

[2] W. Shen, X. Dong, J. Shi, et al: Microporous Mesoporous Mater. Vol. 85 (2005), p.157.

Google Scholar

[3] B. Tian, X. Liu, H. Yang, S. Xie, C. Yu, B. Tu and D. Zhao: Adv. Mater. Vol. 15 (2003), p.1370.

Google Scholar

[4] W. Shen, J. shi, H. Chen, et al: Chem. Lett. Vol. 34 (2005), p.390.

Google Scholar

[5] L.G. Tejuca, J.L.G. Fierro, J.M.D. Tascon: Adv. Catal. Vol. 36 (1989), p.237.

Google Scholar

[6] M. Shokouhimehr, Y. Piao, J. Kim, and et. al.: Angew. Chem. Int. Ed. Vol. 46 (2007), p.1.

Google Scholar

[7] F. Jiao, K.M. Shaju, and P.G. Bruce: Angew. Chem. Int. Ed. Vol. 44 (2005), p.6550.

Google Scholar

[8] T. Valdes-solis, G. marban, and A.B. Fuertes: Chem. Mater. Vol. 17 (2005), p. (1919).

Google Scholar

[9] D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka and G.D. Stucky: Science, Vol. 279, (1998), p.548.

Google Scholar

[10] F. Kleitz, S. H. Choi and R. Ryoo: Chem. Commun. (2003), p.2136.

Google Scholar