Influence of Oxide Morphologies on the Galvanizability of the Third Generation Automotive Steel

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Abstract:

Focusing on improving the galvanizability of the third generation automotive steel, the effect of surface oxides morphologies on the galvanizability was studied. The results show that the surface oxide types of sample steels by XPS analysis after annealing in different conditions are the same, only MnO and Cr2O3 were detected and no complex oxides exist on the surface. Morphologies of surface oxides can greatly influence the galvanizability of the third generation automotive steel, nodule-like oxides surface can contribute to better wettability and inhibition layer than vitreous film-like oxides surface. Galvanizing panels of nodule-like oxides surface steels only show pinhole-sized bare spots, while panels galvanized from vitreous film-like oxide surface steels reveal larger areas of bare spots and uncoated areas. Inhibition layer observed in galvanizing panels of nodule-like oxides surface steels are compact but not homogeneous, some inhibition layer grains are fine, and others are coarse. While the inhibition layer grains of panels galvanized from vitreous film-like oxide surface steels have a non-compact morphology with some particularly fine equiaxed crystals which developed deficiently.

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Advanced Materials Research (Volumes 887-888)

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233-239

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February 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Cao W Q, Wang C, Wang C Y, et al. Microstructures and mechanical properties of the third generation automobile steels fabricated by ART-annealing[J]. Science China Technological Sciences, 2012, 55(7): 1814-1822.

DOI: 10.1007/s11431-012-4877-7

Google Scholar

[2] Dong H, Cao W Q, Shi J, , et al. Control technology of microstructure and properties of the third generation of automotive steel[J]. iron, 2011, 46(6): 1-11.

Google Scholar

[3] Olefjord I, Leijon W, Jelvestam U. Selective surface ace oxidation during annealing of steel sheets in H2/N2 [J]. Applications of surface science, 1980, 6(3): 241-255.

DOI: 10.1016/0378-5963(80)90015-x

Google Scholar

[4] Grabke, H.J., V. Leroy and H. Viefhaus, Segregation on the Surface of Steels in Heat Treatment and Oxidatio. ISIJ international, 1995. 35(2): pp.95-113.

DOI: 10.2355/isijinternational.35.95

Google Scholar

[5] Drillet, P., et al., Selective oxidation of high Si, Mn and Al steel grades during recrystallization annealing and steel/Zn reactivity. Revue de Métallurgie, 2004. 101(10): pp.831-837.

DOI: 10.1051/metal:2004154

Google Scholar

[6] Bellhouse, E.M. and J.R. McDermid, Analysis of the Fe–Zn interface of galvanized high Al–low Si TRIP steels. Materials Science and Engineering: A, 2008. 491(1): pp.39-46.

DOI: 10.1016/j.msea.2007.12.033

Google Scholar

[7] Maki, J., et al., Galvanisability of silicon free CMnAl TRIP steels. Materials science and technology, 2003. 19(1): pp.125-131.

DOI: 10.1179/026708303225009300

Google Scholar

[8] Bordignon, L. and J. Crahay, Dynamic effects in galvanising of high strength steels. Proceedings of Galvatech, Brussels, Belgium, 2001: p.573.

Google Scholar

[9] Strohmeier B R, Hercules D M. Surface spectroscopic characterization of manganese/aluminum oxide catalysts[J]. The Journal of Physical Chemistry, 1984, 88(21): 4922-4929.

DOI: 10.1021/j150665a026

Google Scholar

[10] J.F. Moulder, W.F. Stickle, P.E. Sobol, K.D. Bomber, Handbook of X-ray. Photoelectron Spectroscopy, Perkin-Elmer Corp., Eden Prairie, MN, 1995).

Google Scholar

[11] Norden, M., et al., The change of steel surface chemistry regarding oxygen partial pressure and dew point. Applied Surface Science, (2013).

DOI: 10.1016/j.apsusc.2012.12.103

Google Scholar

[12] Blumenau, M., et al., Impact of selective oxidation during inline annealing prior to hot-dip galvanizing on Zn wetting and hydrogen-induced delayed cracking of austenitic FeMnC steel. Surface and Coatings Technology, 2011. 206(2): pp.542-552.

DOI: 10.1016/j.surfcoat.2011.07.081

Google Scholar

[13] Alibeigi, S., et al., Reactive wetting of high Mn steels during continuous hot-dip galvanizing. ActaMaterialia, 2011. 59(9): pp.3537-3549.

DOI: 10.1016/j.actamat.2011.02.027

Google Scholar

[14] Blumenau, M., et al., Use of pre-oxidation to improve reactive wetting of high manganese alloyed steel during hot-dip galvanizing. Surface and Coatings Technology, 2011. 206(2): pp.559-567.

DOI: 10.1016/j.surfcoat.2011.07.088

Google Scholar

[15] Li Y P, Jiang S M, Zhang Q F , Effect of dual phase steel aluminum content on the morphology of the surface oxide and inhibition layer. Journal of iron and Steel Research. 2012. 24(5): pp.29-34.

Google Scholar

[16] Li, Y., et al., Influence of soaking duration on the selective oxidation and galvanizability of a high‐strength dual phase steel. Surface and Interface Analysis, 2012. 44(4): pp.472-477.

DOI: 10.1002/sia.3829

Google Scholar

[17] Neil Gao, et al., optimizing bath Al level for improved galvanizability of advanced high strength steels. Galvatech'(2011).

Google Scholar

[18] Eynde, X.V., J.P. Servais and M. Lamberigts. Surface oxide maturation and self-reduction: a new process to ensure TRIP steel hot dip galvanizing. inGalvatech. (2004).

Google Scholar

[19] Bellhouse, E.M., A. Mertens and J.R. McDermid, Development of the surface structure of TRIP steels prior to hot-dip galvanizing. Materials Science and Engineering: A, 2007. 463(1): pp.147-156.

DOI: 10.1016/j.msea.2006.09.117

Google Scholar

[20] Blumenau, M., et al., Reactive wetting during hot-dip galvanizing of high manganese alloyed steel. Surface and Coatings Technology, 2011. 205(10): pp.3319-3327.

DOI: 10.1016/j.surfcoat.2010.11.053

Google Scholar

[21] Sagl, R., et al., The role of surface oxides on annealed high-strength steels in hot-dip galvanizing. Corrosion Science, (2013).

DOI: 10.1016/j.corsci.2013.01.039

Google Scholar

[22] Kavitha, R. and J.R. McDermid, On the in-situ aluminothermic reduction of manganese oxides in continuous galvanizing baths. Surface and Coatings Technology, (2012).

DOI: 10.1016/j.surfcoat.2012.09.038

Google Scholar