Characterization of PVDF-HFP-LiCF3SO3-ZrO2 Nanocomposite Polymer Electrolyte Systems

Salmiah Ibrahim; Siti Aishah Hashim Ali; Mohamed Nor Sabirin

doi:10.4028/www.scientific.net/AMR.93-94.489

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 93-94Characterization of PVDF-HFP-LiCF3SO3-ZrO2...

Characterization of PVDF-HFP-LiCF₃SO₃-ZrO₂ Nanocomposite Polymer Electrolyte Systems

Abstract:

Nanocomposite polymer electrolytes were prepared by incorporating different amounts of zirconium oxide (ZrO2) nanofiller to poly(vinylidene fluoride-co-hexafluoropropylene)-lithium trifluoromethane sulfonate (PVDF-HFP-LiCF3SO3). X-ray diffraction (XRD) study has been carried out to investigate the structural features of the electrolyte films while a.c. impedance spectroscopy has been performed to investigate their electrical properties. The conductivity of nanocomposite polymer electrolyte systems is influenced by nanofiller concentration. The increase in conductivity is attributable to the increase in the fraction of amorphous region and the number of charge carriers and vice versa. The highest conductivity obtained is in the order of 10-3 S cm-1 for the system dispersed with 5 wt% of ZrO2 nanofiller.

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Periodical:

Advanced Materials Research (Volumes 93-94)

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489-492

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https://doi.org/10.4028/www.scientific.net/AMR.93-94.489

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January 2010

Authors:

Salmiah Ibrahim, Siti Aishah Hashim Ali, Mohamed Nor Sabirin

Keywords:

Conductivity, Dielectric, X-Ray Diffraction (XRD)

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References

[1] M.B. Armand, Polymer Electrolyte Reviews I, J. R MacCallum and C. A Vincent (Eds) Elsevier, London (1987) p.1.

Google Scholar

[2] C.A. Vincent, Prog of Solid State Chemistry Vol. 17 (1987), p.145.

Google Scholar

[2] F.M. Gray Solid Polymer Electrolytes, Fundamental and Technological Applications VCH New York (1991).

Google Scholar

[4] M. Morita, H. Noborio, N. Yoshimoto, M. Ishikawa, Solid State Ionics Vol. 177 (2006), p.715.

Google Scholar

[5] W. Wieczorek, J.R. Stevens, Z. Florjanczyk, Solid State Ionics Vol . 85 (1996), p.67.

Google Scholar

[6] A.S. Best, A. Ferry, D.R. MacFarlane, M. Forsyth, Solid State Ionics Vol. 126 (1999), p.269.

Google Scholar

[7] H.Y. Sun, Y. Takeda, N. Imanishi, O. Yamamoto, H.J. Sohn, J. Electrochem. Soc. Vol. 147 (2000), p.2462.

Google Scholar

[8] J. -H. Shin, F. Alessandrini, S. Passerini, J. Electrochem. Soc. Vol. 152 (2005), p. A283.

Google Scholar

[9] J.M. Tarascon, A.S. Godz, C.N. Schmutz, F. Shukoki, P.C. Warren Solid State Ionics Vol. 86 (1996), p.49.

Google Scholar

[10] N.S. Mohamed, S. Amir, S.A. Hashim Ali, International Journal of Materials Sciences Vol. 1 (2006), p.111.

Google Scholar

[11] A. Bhide, K. Hariharan, European Polymer Journal Vol. 43 (2007), p.4253.

Google Scholar

[12] R. Mishra and K.J. Rao, Solid State Ionics Vol. 106 (1998), p.113.

Google Scholar

[13] B. Natesan, N.K. Karan, R. S Katiyar, Physical Review E Vol. 74 (2006), p.042801.

Google Scholar

[14] Y-J. Wang, D. Kim, Electrochimica Acta Vol. 52 (2007), p.3181.

Google Scholar

[15] N.T. K Sundaram, T. Vasudevan, A. Subramania, J. Physics and Chemistry of Solids Vol. 68 (2007), p.264.

Google Scholar