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Living Radical Polymerization of Methyl Methacrylate Mediated by Tris-(4-Acetyphenyl)Methane

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Abstract:

Pseudo-living radical polymerization and reverse atom transfer radical polymerization (RATRP) of methyl methacrylate (MMA) were reported, utilizing tris-(4-acetyphenyl) methane (TAcPM) as the thermal iniferter and initiator, respectively. The polymerization of MMA using TAcPM as thermal iniferter possesses pseudo-living characteristics: Mn increases with conversion in a certain range, and the resulted polymer can be used as the macro-initiator for chain extension. The RATRP using TAcPM as the initiator shows linear kinetic plot, linear increase of Mn with conversion and narrow polydispersity indice (PDI) of the resultant polymers.

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Periodical:

Advanced Materials Research (Volume 933)

Pages:

91-96

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.933.91

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Online since:

May 2014

Authors:

Yuan Qing Xu*, Tao Ding, Xiao Min Fang, Hao Xu, Yan Rong Ren

Keywords:

Iniferter, Pseudo-Living Radical Polymerization, Reverse Atom Transfer Radical Polymerization, Tris-(4-acetyphenyl) Methane

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] F. di Lena, K. Matyjaszewski, Prog. Polym. Sci. 35 (2010) 959.

Google Scholar

[2] T. Otsu, M. Yoshida, Makromol. Chem. Rapid Commun. 3 (1982) 127.

Google Scholar

[3] T. Otsu, J. Polym. Sci. Part A Polym. Chem. 38 (2000) 2121.

Google Scholar

[4] M. K. Georges, R. P. N. Veregin, P. M. Kazmaier, G. K. Hamer, Macromolecules 26 (1993) 2987.

Google Scholar

[5] J. S. Wang, K Matyjaszewski, J. Am. Chem. Soc. 117 (1995) 5614.

Google Scholar

[6] M. Kato, M. Kamigaito, M. Sawamoto, T. Higashimura, Macromolecules 28 (1995) 1721.

Google Scholar

[7] J. Chiefari, Y. K. Chong, F. Ercole, et al., Macromolecules 31 (1998) 5559.

Google Scholar

[8] D. Charmot, P. Corpart, H. Adam, S. Z. Zard, et al., Macromol. Symp. 150 (2000) 23.

DOI: 10.1002/1521-3900(200002)150:1<23::aid-masy23>3.0.co;2-e

Google Scholar

[9] K. Matyjaszewski, Macromol. Rapid Commun. 26 (2005) 135.

Google Scholar

[10] S. Qin, K. Qiu, Acta Polym. Sin. 2 (2002) 127.

Google Scholar

[11] A. Kongkaew, J. Wootthikanokkhan, Polym. Bull. 43 (1999) 327.

Google Scholar

[12] T. Otsu, A. Kuriyama, Polym. Bull. 11 (1984) 135.

Google Scholar

[13] T. Otsu, K. Yamashita, K. Tsuda, Macromolecules 19 (1986) 287.

Google Scholar

[14] P. K. Ivanova-Mitseva, V. Fragkou, et al., Macromolecules 44 (2011) 1856.

Google Scholar

[15] A. Kuriyama, T. Otsu, Polym. J. 16 (1984) 511.

Google Scholar

[16] D. Braun, S. Steinhauer-Beiber, Euro. Polym. J. 33 (1997) 7.

Google Scholar

[17] A. R. Kannurpatti, S. Lu, G. M. Bunker, C. N. Bowman, Macromolecules 29 (1996) 7310.

Google Scholar

[18] J. Lokaj, A. Sikora, P. Holler, O. Konečný, J. Appl. Polym. Sci. 67 (1998), 755.

Google Scholar

[19] T. Tazaki, T. Otsu, Polym. Bull. 17 (1987) 127.

Google Scholar

[20] S. H. Qin, K. Y. Qiu, G. Swift, et al., J. Polym. Sci. Part A Polym. Chem. 37 (1999) 4610.

Google Scholar

[21] X. P. Chen, K. Y. Qiu, G. Swift, D. G. Westmoreland, S. Wu, Euro. Polym. J. 36 (2000) 1547.

Google Scholar

[22] S. H. Qin, K. Y. Qiu, Polym. Bull. 44 (2000) 123.

Google Scholar

[23] M. Kumar, T. Kannan, Polym. J. 42 (2010) 916.

Google Scholar

[24] H. Zhou, J. Jiang, K. Zhang, J. Polym. Sci. Part A Polym. Chem. 43 (2005) 2567.

Google Scholar

[25] T. Otsu, T. Tazaki, Polym. Bull. 16 (1986) 277.

Google Scholar

[26] M. H. Acar, Y. J. Yagcl, Macromol. Sci. A Chem. 28 (1991) 177.

Google Scholar

[27] E. V. Chernikova, Z. A. Pokataeva, E. S. Garina, et al., Macromol. Chem. Phys. 202 (2001) 188.

Google Scholar

[28] K. Matyjaszewski, J. H. Xia, Chem. Rev. 101 (2001) 2921.

Google Scholar

[29] J. S. Wang, K. Matyjaszewski, Macromolecules 28 (1995) 7901.

Google Scholar

[30] R. W. Simms, M. F. Cunningham, Macromolecules 40 (2007) 860.

Google Scholar

[31] J. S. Wang, K. Matyjaszewski, Macromolecules 28 (1995) 7572.

Google Scholar

[32] J. H. Xia, K. Matyjaszewski, Macromolecules 30 (1997) 7692.

Google Scholar

[33] G. Moniteau, P. Dubois, R. Jerome, T. Senninger, P. Teyssie, Macromolecules 31 (1998) 545.

Google Scholar

[34] J. Gromada, K. Matyjaszewski, Macromolecules 34 (2001) 7664.

Google Scholar

[35] M. Li, K. Min, K. Matyjaszewski, Macromolecules 37 (2004) 2106.

Google Scholar

[36] M. Li, NM. Jahed, K. Min, K. Matyjaszewski, Macromolecules 37 (2004) 2434.

Google Scholar

[37] L. Mueller, W. Jakubowski, K. Matyjaszewski, Euro. Polym. J. 47 (2011) 730.

Google Scholar

[38] W. Jakubowski, K. Matyjaszewski, Macromolecules 38 (2005) 4139.

Google Scholar

[39] L. J. Bai, L. F. Zhang, Z. B Zhang, et al., Macromolecules 43 (2010) 9283.

Google Scholar

[40] W. Jakubowski, K. Min, K. Matyjaszewski, Macromolecules 39 (2006) 39.

Google Scholar

[41] K. Min, H. F. Gao, K. Matyjaszewski, Macromolecules 40 (2007) 1789.

Google Scholar

[42] R. Nicolay, Y. Kwak, K. Matyjaszewski, Angew. Chem. 122 (2010) 551.

Google Scholar

[43] X. P. Chen, K. Y. Qiu, Polym. Int. 49 (2000) 1529.

Google Scholar

[44] Y. Kwak, K. Matyjaszewski, Macromolecules 41 (2008) 6627.

Google Scholar

[45] X. P. Chen, K. Y. Qiu, New J. Chem. 24 (2000) 865.

Google Scholar

[46] D. Q. Qin, S. H. Qin, X. P. Chen, K. Y. Qiu, Polymer 41 (2000) 7347.

Google Scholar

[47] S. H. Qin, D. Q. Qin, K. Y. Qiu, New J. Chem. 25 (2001) 893.

Google Scholar

[48] D. Q. Qin, S. H. Qin, K. Y. Qiu, Macromolecules 33 (2000) 6987.

Google Scholar

[49] G. N. Lewis, D. Lipkin, T. T. Nagel, J. Am. Chem. Soc. 66 (1994) 1579.

Google Scholar

[50] G. Porter, E. Strachan, Trans. Faraday Soc. 54 (1958) 1595.

Google Scholar

[51] L. Harris, J. Kaminsky, R. G. Simard, J. Am. Chem. Soc. 57 (1935) 1151.

Google Scholar

[52] L. E. Manring, K. S. Peters, J. Phys. Chem. 88 (1984) 3516.

Google Scholar

[53] Y. Q. Xu, J. M. Lu, N. J. Li, et al., Eur. Polym. J. 44 (2008) 2404.

Google Scholar

[54] Y. Q. Xu, Q. F. Xu, J. M. Lu, et al., Polym. Bull. 58 (2007) 809.

Google Scholar

[55] J. Kwak, P. Lacroix-Desmazes, J. J. Robin, B. Boutevin, N. Torres, Polymer 44 (2003) 5119.

Google Scholar

[56] Y. Q. Xu, J. M. Lu, Q. F. Xu, L. H. Wang, Euro. Polym. J. 41 (2005) 2422.

Google Scholar

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