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Electrosyntheses of Poly(selenophene-co-3-methylthiophene) with Improved Thermoelectric Property in Boron Trifluoride Diethyl Etherate

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Abstract:

Novel poly (selenophene-co-3-methylthiophene) was successfully achieved by directly electrochemical oxidation of the monomer mixtures of selenophene and 3-methylthiophene (3MeT) in boron trifluoride diethyl etherate. The effect of monomer concentration ratios on the copolymerization were investigated by cyclic voltammetry. The structures of as-prepared copolymers were characterized by UV-vis and infrared spectroscopy. The conductivity and thermoelectric measurements revealed the incorporation of 3MeT into the polyselenophene (PSe) chain improved significantly the conductivity and thermoelectric property of PSe.

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Periodical:

Advanced Materials Research (Volume 937)

Pages:

17-22

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.937.17

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Online since:

May 2014

Authors:

Sheng Tao Wang, Bao Yang Lu, Jing Kun Xu*, Wei Qiang Zhou

Keywords:

Conducting Polymer, Electrochemical Copolymerization, Poly(3-methylthiophene), Polyselenophene, Thermoelectric Property

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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