Preparation and Characterization of Resin-Derived Carbon Foams Containing Hollow Microspheres

Article Preview

Abstract:

Resin-derived carbon foams with closed hollow spherical structure were prepared from mixtures of hollow phenolic microspheres and phenolic resin, followed by curing and carbonization. The resultant carbon foam had a bulk density of 0.45 g·cm-3. Effects of hollow microsphere on the on the compressive property and thermal conductivity of carbon foams were investigated. The results revealed that the hollow microspheres played an important role in improving compressive fracture toughness and lowering the thermal conductivity of carbon foams. The compressive fracture characteristics of carbon foam exhibited gradient brittle fracture, and the compressive strength was 10.93 MPa. The thermal conductivity of the carbon foam was 0.907 W·m-1·K-1 at room temperature, which was lowered by 49.67 % in comparison with phenolic-based vitreous carbon.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 941-944)

Pages:

318-323

Citation:

Online since:

June 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A.M. Druma, M.K. Alam and C. Druma, Analysis of thermal conduction in carbon foams, Int. J. Therm. Sci. 43 (2004) 689-695.

DOI: 10.1016/j.ijthermalsci.2003.12.004

Google Scholar

[2] X. Wang, J. Zhong, Y. Wang and M. Yu, A study of the properties of carbon foam reinforced by clay, Carbon. 44 (2006) 1560-1564.

DOI: 10.1016/j.carbon.2005.12.025

Google Scholar

[3] N.C. Gallego, J.W. Klett, Carbon foams for thermal management, Carbon. 41 (2003) 1461-1466.

DOI: 10.1016/s0008-6223(03)00091-5

Google Scholar

[4] H. Shen, S. Nutt, Mechanical characterization of short fiber reinforced phenolic foam, Composites A. 34 (2003) 899-906.

DOI: 10.1016/s1359-835x(03)00136-2

Google Scholar

[5] M. Liu, L. Gan and F. Zhao, Carbon foams with high compressive strength derived from polyarylacetylene resin, Carbon. 45 (2007) 3055-3057.

DOI: 10.1016/j.carbon.2007.10.003

Google Scholar

[6] S. Lei, Q. Guo and J. Shi, Study on the heat treatment process of phenolic foam precursor, Journal of Materials Engineering. (2007) 216-220. (In Chinese).

Google Scholar

[7] E. M. Wouterson, F. Y. C Boey and X. Hu, Effect of fiber reinforcement on the tensile, fracture and thermal properties of syntactic foam, Polymer. 48 (2007) 3183-3191.

DOI: 10.1016/j.polymer.2007.03.069

Google Scholar

[8] E. Bruneton, C. Tallaron, N. Gras-Naulin and A. Cosculluela, Evolution of the structure and mechanical behaviour of a carbon foam at very high temperatures, Carbon. 40 (2002) 1919-(1927).

DOI: 10.1016/s0008-6223(02)00003-9

Google Scholar

[9] Y.W. Zhang, M. Jiang, J. X. Zhao and J. Y. Wang, Preparation of thermo-sensitive core-shell polymeric nanospheres via in situ, polymerization method, Acta Polym Sinica. (2007) 136 -143. (In Chinese).

Google Scholar

[10] C. D. Liang and S. Dai, Synthesis of mesoporous carbon materials via enhanced hydrogen-bonding interaction, J. Am. Chem. Soc. 128 (2006) 5316-5317.

DOI: 10.1021/ja060242k

Google Scholar

[11] Z. H. Min, M. Cao and S. Zhang, Effect of precursor on the pore structure of carbon foams, New Carbon Materials. 22 (2007) 75-79.

DOI: 10.1016/s1872-5805(07)60009-2

Google Scholar

[12] R. Y. Luo,Y. F. Ni and J. S. Li, The mechanical and thermal insulating properties of resin-derived carbon foams reinforced by K2Ti6O13 whiskers, Mater. Sci. Eng. A. 528 (2011) 2023-(2027).

DOI: 10.1016/j.msea.2010.10.106

Google Scholar

[13] L. Y. Zhang, J. Ma, Effect of coupling agent on mechanical properties of hollow carbonmicrosphere/phenolic resin syntactic foam, Compos. Sci. Technol. 70 (2010) 1265-1271.

DOI: 10.1016/j.compscitech.2010.03.016

Google Scholar

[14] E. M. Wouterson, F. Boey and X. Hu, Specific properties and fracture toughness of syntactic foam: Effect of foam microstructures, Compos. Sci. Technol. 65 (2005) 1840-1850.

DOI: 10.1016/j.compscitech.2005.03.012

Google Scholar

[15] N. Gupta, R. Maharsia, Enhancement of Energy Absorption in Syntactic Foams by Nanoclay Incorporation for Sandwich Core Applications, Appl. Compos. Mater. 12 (2005) 247-261.

DOI: 10.1007/s10443-005-1130-6

Google Scholar

[16] B. Wang, H.J. Li and L.J. Guo, Preparation and properties of precursor of phenolic-based carbon foams, Journal of Solid Rocket Technology. 37 (2014) 113-117. (In Chinese).

Google Scholar

[17] A. Celzard, W. Zhao and A. Pizzi, Mechanical properties of tannin-based rigid foams under-going compression, Mater. Sci. Eng. A. 527 (2010) 4438-4446.

DOI: 10.1016/j.msea.2010.03.091

Google Scholar

[18] X. W. Wu, M. H. Fang and L. F. Mei, Effect of final pyrolysis temperature on the mechanical and thermal properties of carbon foams reinforced by aluminosilicate, Mater. Sci. Eng. A. 558 (2012) 446-450.

DOI: 10.1016/j.msea.2012.08.025

Google Scholar