Photochromism and Fluorescent of a Novel Diarylethene Bearing Methylpyridine Group

Article Preview

Abstract:

A new unsymmetrical photochromic diarylethene compound, 1-(2-methyl-3-benzofuranyl)-2-[2-methyl-5-(2-methyl-6-pyridyl)-3-thienyl] perfluorocyclopentene (1o), was synthesized and its photochemical, fluorescence properties were investigated systematically both in solution and PMMA amorphous film. The photochromic reaction kinetics results indicated that the cyclization processes of 1o belong to the zeroth order reaction and the cycloreversion process belong to the first order reaction.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

105-108

Citation:

Online since:

May 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] S. Kawata and Y. Kawata: Chem. Rev. Vol. 100 (2000), p.1777.

Google Scholar

[2] D. M. Eiger, C. P. Lutz and W. E. Rudge: Nature. Vol. 325 (1991), p.600.

Google Scholar

[3] T. Yamaguchi and M. Irie: Tetrahedron Lett. Vol. 47 (2006), p.1267.

Google Scholar

[4] G. Liu, S. Z. Pu and R. J. Wang: J. Org. Lett. Vol. 15 (2013), p.980.

Google Scholar

[5] T. Yamaguchi and M. Irie: J Photochem. Photobiol. A Vol. 178 (2006), p.162.

Google Scholar

[6] S. Lee, You, Y. Ohkubo and K. Fukuzumi.: Angew. Chem. Int. Ed. Vol. 51 (2012), p.1.

Google Scholar

[7] K. Yumoto, M. Irie and Matsuda, K: Org. Lett. Vol. 10 (2008), p. (2051).

Google Scholar

[8] S. Q. Cui, S. Z. Pu and G. Liu: Dyes Pigm. Vol. 91 (2011), p.435.

Google Scholar

[9] G. Liu, M. Liu, S. Z. Pu, C. B. Fan and Cui, S. Q : Dyes Pigm. Vol. 95 (2012), p.553.

Google Scholar

[10] S. Z. Pu, G. Liu and J. K. Xu: Org. Lett. Vol. 9 (2007), p.2139.

Google Scholar

[11] A. Osuka, D. Fujikane, H. Shinmori and M. Irie: J. Org. Chem. Vol. 66 (2001), p.3913.

Google Scholar

[12] C. B. Fan, W. J. Miao and G. Liu: Dyes and Pigments. Vol. 84 (2009), p.25.

Google Scholar

[13] S. Z. Pu, W.J. Liu and W. J. Miao: J. Phys. Org. Chem. Vol. 22 (2000), p.954.

Google Scholar