Waste Steel-Pickling Sulphuric Acid Removal Treated by Freezing Crystallization-Acid Retardation Coupling Technology

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Abstract:

Waste steel-pickling sulphuric acid was treated by freezing crystallization acid retardation coupling technology. Under the optimal conditions(temperature was -5 °C, rotational speed was 4000 rpm, TulsionA-32 as Acid Retardation reagent), the concentration of sulfuric acid reached 20~25 % and the concentration of FeSO4·7H2O fell to 15~20 g/L in the waste steel-pickling sulphuric acid which achieved the standard for sulfuric acid reuse. Polymeric ferric sulfate prepared by recyclable ferrous sulfate was accord with the first type of standard water clarfying agent polymer ferric sulfate(GB14591-2006).

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Advanced Materials Research (Volumes 955-959)

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2915-2918

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June 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Hua W,Li C R,Zhang X,et al. Separation of H2SO4/FeSO4 mixture by spiral wound diffusion dialysis[J] Chemical Industry and Engineering Progress,2012,31 (1): 222-226(in Chinese).

Google Scholar

[2] Wei C,Li X B,Deng Z G. Recovery of H2SO4 from an acid leach solution by diffusion dialysis[J] J. Hazardous Materials,2010,176: 226-230.

DOI: 10.1016/j.jhazmat.2009.11.017

Google Scholar

[3] Sheng H L,Mu C L. Recovery of sulfuric acid from waste aluminum surface processing solution by diffusion dialysis[J] J. Hazard Mater. 1998,60: 247-257.

Google Scholar

[4] Wan J B. New disposition technology of waste acid liquor by nanofiltration[J] Membrane Science and Technology,2000,20(3): 59-61(in Chinese).

Google Scholar

[5] Munns, W. K. Iron Removal from Pickle Liquors using Absorption Resin Technology. In Iron Control in Hydrometallurgy; Dutrizac, J. E., Ed., Ellis Horwood Ltd.: Chichester, U.K., 1984; p.26.

Google Scholar

[6] Hatch, M. J.; Dillon, J. A. Acid Retardation. Ind. Eng. Chem. 1963, 2: 253 -263.

Google Scholar