The Performance of Highly Dispersed Au-Pd/ZrO2 Catalyst for Base-Free Synthesis N-Benzylidenebenzylamine

Article Preview

Abstract:

A series of Au/ZrO2, Pd/ZrO2, Au-Pd/ZrO2 catalysts were prepared by the solution reduction method using NaBH4 as reducing agent and L-lysine as protection agent. UV-Visible and XRD were employed to investigate the dispersion, composition and catalytic properties of the catalyst. The results show that Au-Pd/ZrO2 alloy catalyst with high dispersion display higher activity than monometallic Au, monometallic Pd catalyst for the base-fee synthesis of N-Benzylidenebenzylamine.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 955-959)

Pages:

498-501

Citation:

Online since:

June 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Bond, G. C.; Thompson, D. T. Catal. Rev-Sci. Eng. 41, 319. (1999).

Google Scholar

[2] Haruta, M. Catal. Today. 36, 153. (1997).

Google Scholar

[3] Xi Chen, Huai Yong Zhu, Jin Cai Zhao, Zhan Feng Zheng, and Xue Ping Gao. Angew. Chem. Int. Ed., 47, 5353-5356. (2008).

Google Scholar

[4] Nicolas Marion, Rube´n S. Ramo´n, and Steven P. Nolan. J. AM. CHEM. SOC. 131, 448-449. (2009).

Google Scholar

[5] Xuebin Ke, Sarina Sarina, Jian Zhao, Xingguang Zhang, Jin Chang and Huaiyong Zhu. Chem. Commun. 48, 3509-3511. (2012).

Google Scholar

[6] Sarina Sarina, Huaiyong Zhu, Esa Jaatinen, Qi Xiao, Hongwei Liu, Jianfeng Jia, Chao Chen, and Jian Zhao. J. Am. Chem. Soc. 135, 5793−5801. (2013).

DOI: 10.1021/ja400527a

Google Scholar

[7] F. Gao, D.W. Goodman, Chem Soc Rev. 41, 8009. (2012).

Google Scholar

[8] Wenjing Cui, Bao Zhaorigetu, MeilinJia, Wulan ao, and Huaiyong Zhu. RSC. Adv. 4, 2061-2064, (2014).

Google Scholar

[9] Wenjing Cui, Wulan Ao, Yulin Zhang, and Bao Zhaorigetu. Advanced Materials Research. 716, 89-93. (2013).

Google Scholar

[10] Huaiyong Zhu, Xuebin Ke, Xuzhuang Yang, Sarina Sarina, and Hongwei Liu. Angew. Chem. Int. Ed. 49, 9657-9661. (2010).

DOI: 10.1002/anie.201003908

Google Scholar

[11] K. Patel, S. Kapoor, D.P. Dave, T. Mukherjee, Res. Chem. Intermed. 32, 103-113. (2006).

Google Scholar