The Forming of Model Colloid System

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The paper reports on the creation of a model colloid test system which is similar to groundwater and it can be used as a test system in the water treatment. It is found that at the molar ratio iron/silicon/organic substance is equal to1/7/2 and two orders such as organic substances-Si-Fe and Si-organic substances-Fe, stable colloid system is formed. The mechanism of formation of iron colloid system is described by three steps. The first is the formation of the organosilicon complexes. The second is oxidation of the iron and forming of Fe (OH)3. The last is forming a sol at zeta potential is - 35 mV with electrostatic interaction.

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Advanced Materials Research (Volumes 971-973)

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266-269

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June 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] E. B Sirota, Complete phase-diagram of a charged colloidal system - A synchrotron X-ray scattering study, Physical Review Letters (1989) 1524-1527.

DOI: 10.1103/physrevlett.62.1524

Google Scholar

[2] A. Yethiraj, A. Blaaderen, A colloidal model system with an interaction tunable from hard sphere to soft and dipolar, Letters to Nature (2003) 513-517.

DOI: 10.1038/nature01328

Google Scholar

[3] L.V. Serikov, L.N. Shiyan, E.A. Tropina, N.V. Vidiaykina, F.H. Frimmel, G. Metreveli, Colloid system of groundwater of the West Siberian region, Bulletin of the Tomsk Polytechnic University (2006) 27-31.

Google Scholar

[4] Salanko J.T., Lakso E.J., Kamula R.L. (2007) The effect of ozonation on the size fractions of iron and total organic carbon in groundwater. Journal of Environmental Science and Health Part A 42: 795–801.

DOI: 10.1080/10934520701304500

Google Scholar

[5] G. Cardenas, V. Delgado, Iron colloids prepared by chemical liquid deposition, Journal of the Chilean Chemical Society (2010) 301-303.

DOI: 10.4067/s0717-97072010000300004

Google Scholar

[6] L.V. Serikov, L.N. Shiyan, E.A. Tropina, P.A. Xriyapov, G.G. Saveliev, G. Metreveli, Colloid–chemical properties of iron connections in natural waters systems of the groundwaters in the Western - Siberian region, Bulletin of the Tomsk Polytechnic University (2010).

Google Scholar

[7] L.V. Serikov, E.A. Tropina, L.N. Shiyan, F.H. Frimmel, G. Metreveli, M. Delay, Iron oxidation in different types of groundwater of Western Siberia, Journal for Soils and Sediments (2009) 103-110.

DOI: 10.1007/s11368-009-0069-x

Google Scholar

[8] L.N. Shiyan, K.I. Machekhina, E.A. Tropina, E.N. Gryaznova, V.V. An, Effect of Humic Substances and Silicon Ions on Stability of Iron Hydroxide (III) Nanoparticles, Advanced Material Research (2013) 232-237.

DOI: 10.4028/www.scientific.net/amr.872.237

Google Scholar

[9] I. V Perminova, F.H. Frimmel, A.V. Kudryavtsev, N.A. Kulikova., G. Abbt-Braun, S. Hesse, V.S. Petrosyan, Molecular weight characteristics of humic substances from different environments as determined by size exclusion chromatography and their statistical evaluation, Environ. Sci. Technology (2003).

DOI: 10.1021/es0258069

Google Scholar

[10] K.I. Machekhina, L.N. Shiyan, , E.A. Tropina, A. Klupfel, Study processes of ultra- and nanofiltration of iron colloid solution, Bulletin of the Tomsk Polytechnic University (2011) 27-30.

Google Scholar

[11] C. H Paul., R. Raj, Principles of Colloid and Surface Chemistry, Marcel Dekker, New York, (1997).

Google Scholar

[12] B.V. Eremenko, M.L. Malysheva, V.P. Sambur, Stability of water dispersions of micro powders of titanium carbide in electrolyte solutions, Colloid magazine (1989) 25–35.

Google Scholar